菌株异质性和扩展缺陷在化矿矿器件的设备
Kieran W P Orr1,2, Jiecheng Diao3, Krishanu Dey1
1Department of Physics, Cavendish Laboratory, University of Cambridge, JJ Thomson Avenue, Cambridge CB3 0HE, U.K.
概括
应变显著影响化物矿太阳能电池的性能. 这项研究揭示了矿颗粒内的纳米级菌株异质性,为设备效率和稳定性提供了新的见解.
科学领域:
- 材料科学 材料科学 材料科学
- 固态物理 固态物理
- 光电学是指光电子产品.
背景情况:
- 应变对于光电学中的化矿半导体性能至关重要.
- 当前的菌株分析经常使用大规模平均值,缺少对器件功能至关重要的纳米级异质性.
研究的目的:
- 为了研究功能太阳能电池内的化矿吸收器中的纳米级菌株分布.
- 揭示谷内和谷内菌株的变异及其起源.
主要方法:
- 采用了使用布拉格连贯衍射成像的三维纳米级菌株映射.
- 在Cs0.1FA0.9Pb(I0.95Br0.05)3和Cs0.15FA0.85SnI3的矿太阳能电池中分析了单个颗粒.
主要成果:
- 发现了显著的局部菌株和在谷物内和谷物之间引人注目的异质性.
- 确定了拉力和压力应变的独特区域.
- 观察到有规律的位移以及Cs0.15FA0.85SnI3中反相边界形成的证据.
结论:
- 在设备中的化物矿中,纳米级菌株高度异质.
- 了解这些局部菌株是优化矿太阳能电池效率和稳定的关键.
- 对缺陷的直接成像,如位移,为材料改进提供了关键数据.
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