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Updated: Jun 23, 2025

Controlled Photoredox Ring-Opening Polymerization of O-Carboxyanhydrides Mediated by Ni/Zn Complexes
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Published on: November 21, 2017

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CO2 基聚碳酸通过循环碳酸的环开聚合,由 NHC 基复合物促进

Federica Tufano1,2, Claudia Napolitano1,2, Mina Mazzeo1,2

  • 1Department of Chemistry and Biology "Adolfo Zambelli" University of Salerno, via Giovanni Paolo II, 132, 84084 Fisciano, SA, Italy.

Biomacromolecules
|June 25, 2024
PubMed
概括

一种新型的N-异环碳酸催化剂使三甲烯碳酸盐 (TMC) 的受控环开放聚合变为多甲烯碳酸盐 (PTMC) 成为可能. 这种方法产生了可调节的分子质量和低分散度的聚合物,最大限度地减少了副作用.

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