模拟区域缺陷对多聚合物 (VDF-Co-TrFE) 共聚合物的电热效应的影响
Vadim I Sultanov1, Vadim V Atrazhev1, Dmitry V Dmitriev1
1N. M. Emanuel Institute of Biochemical Physics of Russian Academy of Sciences, 4 Kosygin Street, Moscow 119334, Russia.
铁电聚 ((维尼利二二化物-co-trifluoroethylene) [poly ((VDF-co-TrFE)) 的区域缺陷改变了电热效应. 这些缺陷使相位过渡更加渐进,提高了对聚合物偏振和温度变化的模型准确性.
科学领域:
- 材料科学 材料科学 材料科学
- 凝聚物质物理学 凝聚物质物理学
- 聚合物科学 聚合物科学
背景情况:
- 在poly ((VDF-co-TrFE) 中的电热效应与铁电和电相之间的第一阶段过渡有关.
- 了解影响这种转变的因素对于优化电热材料至关重要.
研究的目的:
- 为了研究区域缺陷对多元{VDF-co-TrFE}电热效应的影响.
- 开发和验证一个包含regiodefects的分析模型,用于预测材料的行为.
主要方法:
- 分子动力学 (MD) 模拟以观察具有区域缺陷的相位过渡行为.
- 为分析模型开发一个修改后的兰道现象学理论.
- 模型参数的校准使用MD模拟的多 ((VDF-co-TrFE) 晶体.
主要成果:
- 区域缺陷将一级阶段过渡转变为一个更加渐进的二级过渡.
- 分析模型准确地预测了聚合物极化 (P) 和附带温度变化 (ΔT) 作为温度,电场和缺陷度的函数.
- 具有regiodefects的模型预测显示与实验数据的一致性明显更好.
结论:
- 区域缺陷在修改多的电热性质方面发挥着至关重要的作用 ((VDF-co-TrFE).
- 开发的分析模型为理解和设计用于电热应用的铁电聚合物提供了有价值的工具.
更多相关视频
06:34Application of a Coupling Agent to Improve the Dielectric Properties of Polymer-Based Nanocomposites
Published on: September 19, 2020
09:17Reductive Electropolymerization of a Vinyl-containing Poly-pyridyl Complex on Glassy Carbon and Fluorine-doped Tin Oxide Electrodes
Published on: January 30, 2015
相关概念视频
Dielectric Polarization in a Capacitor
Electrostatic Boundary Conditions in Dielectrics
Consider a case where both the mediums across a boundary are two different dielectric materials. Recall that the electric field and electric displacement are proportional and related through the material's...
Modeling of Diode Reverse Characteristics
When a reverse voltage applied to a Zener diode exceeds its breakdown voltage, the diode enters the breakdown region. At this point, the...
Modeling of Diode Forward Characteristics
Types of Step-Growth Polymers: Polyesters
Polyesters are commonly prepared from terephthalic acid and ethylene glycol; the crude product is known as poly(ethylene terephthalate) or PET. However, polyesters are synthesized industrially by transesterification of dimethyl terephthalate with ethylene glycol at 150 °C. The two reactants and the...
Induced Electric Dipoles
Since the absolute value of potential energy holds no physical meaning, its zero value can be chosen as per...
