一种可加工的离子凝,具有可热切换导电性
Shoujie Shen1, Jia Li1, Qiyu Wu1
1Key Laboratory of Magnetic Molecules and Magnetic Information Materials (Ministry of Education), School of Chemistry and Material Science, Shanxi Normal University, Taiyuan 030031, Shanxi, China.
概括
我们开发了一种具有导电性的新型离子凝,其导电性随温度的变化而改变. 由于特种离子液体中的triblock共聚合物的自组装,这种材料很容易被加工.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物化学 聚合物化学
- 电化学 电化学 电化学
背景情况:
- 离子凝通过将离子液体与聚合物结合,提供独特的特性.
- 开发具有可调节导电性和良好的可加工性离子凝仍然是一个挑战.
研究的目的:
- 为了创建具有可热切换导电性的离子凝.
- 通过物理自组装和化学交联,在离子凝中实现高可加工性.
主要方法:
- 用于物理自组合的聚乙烯-乙烯氧化物-乙烯-乙烯 (PS-PEO-PS) 三块共聚物.
- 采用混合离子液体系统,其中包含热反应和可聚合的离子液体.
- 可聚合元件的内置化学交叉连接.
主要成果:
- 成功制造出一种具有可热切换导电性的离子凝.
- 证明了由此产生的离子凝的高可加工性.
- 离子凝的特性归因于离子液体矩阵内的三环阻断共聚物的自我组装.
结论:
- 开发的离子凝为需要调节导电性和易于制造的应用提供了有前途的材料.
- 物理自组装和化学交联的结合为设计先进的离子凝提供了一个可行的策略.
更多相关视频
相关概念视频
Electrical Conductivity
1.1K
In perfect conductors, the electric field inside is always zero due to the abundance of free electrons, which nullify any field by flowing. As a result, any residual charge resides on the surface.
In a practical conductor, an applied electric field may be sustained, causing a flow of electrons, which produce a current. The differential form of the current, the current density, is related to the electric field.
More generally, it is related to the force per unit charge, which involves the...
In a practical conductor, an applied electric field may be sustained, causing a flow of electrons, which produce a current. The differential form of the current, the current density, is related to the electric field.
More generally, it is related to the force per unit charge, which involves the...
1.1K
Potentiometry: Types of Electrodes
623
Reference electrodes serve as a stable reference point for potentiometric measurements, while indicator and working electrodes react to variations in the composition of a solution.
The Standard Hydrogen Electrode (SHE) is a widely used reference electrode that maintains zero potential across all temperatures. However, its need for a continuous hydrogen gas supply renders it impractical for everyday use.
An alternative to SHE is the Saturated Calomel Electrode (SCE). This electrode features an...
The Standard Hydrogen Electrode (SHE) is a widely used reference electrode that maintains zero potential across all temperatures. However, its need for a continuous hydrogen gas supply renders it impractical for everyday use.
An alternative to SHE is the Saturated Calomel Electrode (SCE). This electrode features an...
623
Charging Conductors By Induction
7.7K
The Earth is a good conductor of electricity, and it is so big that it can be considered an infinite source or sink of charges. It can easily exchange charges with any matter.
Generally, conductors like metals do not allow any excess charge to be present on them. Any excess charge added to metals easily flows away, for example, when a metal is placed on the Earth. This process is called earthing.
However, conductors can be charged by a process called induction. For example, consider charging a...
Generally, conductors like metals do not allow any excess charge to be present on them. Any excess charge added to metals easily flows away, for example, when a metal is placed on the Earth. This process is called earthing.
However, conductors can be charged by a process called induction. For example, consider charging a...
7.7K
Capacitor With A Dielectric
3.9K
Parallel plate capacitors consist of two conducting plates separated by a certain distance. However, it is mechanically difficult to hold the large plates parallel to each other without actual contact. Hence, a dielectric layer is commonly placed between the plates, which provides an easy solution for holding the plates together with a small gap and increases the capacitance of the capacitor.
Dielectrics are non-conducting materials with no free or loosely bound electrons. When a dielectric is...
Dielectrics are non-conducting materials with no free or loosely bound electrons. When a dielectric is...
3.9K
Potentiometry: Membrane Electrodes
551
Membrane electrodes, also known as p-ion electrodes, use membranes that selectively interact with free analyte ions, generating a potential difference across the membrane. The resulting membrane potential, known as the asymmetry potential, is not zero even when analyte concentrations on both sides of the membrane are equal. The membrane's response is typically not selective to a single analyte but proportional to the concentration of all ions in the sample solution capable of interacting at...
551
Conductors and Insulators
8.5K
Some materials may easily let electrical charges pass through them, while others obstruct their flow. The former are called conductors and the latter insulators. The atomic structures of materials determine whether they are conductors or insulators of electricity.
Most metals are conductors. Their atomic configuration is such that one or more electron(s) are loosely bound to the nucleus in each atom. Thus, a sea of mobile electrons are available in them, known as free electrons. Their easy...
Most metals are conductors. Their atomic configuration is such that one or more electron(s) are loosely bound to the nucleus in each atom. Thus, a sea of mobile electrons are available in them, known as free electrons. Their easy...
8.5K


