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相关概念视频

Isochoric and Isobaric Processes01:21

Isochoric and Isobaric Processes

3.4K
A thermodynamic process that occurs at constant volume is called an isochoric process. According to the first law of thermodynamics, heat supplied or removed from the system is partially utilized to perform work and change the internal energy of the system. However, in an isochoric process, the volume remains constant. Hence, the work done by the system is zero. Therefore, the exchange of heat changes the internal energy of the system only. 
Suppose 1000 g of water is heated from 40...
3.4K
Equilibrium Conditions for a Particle01:23

Equilibrium Conditions for a Particle

1.1K
When an object is in equilibrium, it is either at rest or moving with a constant velocity. There are two types of equilibrium: static and dynamic. Static equilibrium occurs when an object is at rest, while dynamic equilibrium occurs when an object is moving with a constant velocity. In both cases, there must be a balance of forces acting on the object.
To understand the concept of equilibrium, let us first consider the forces acting on an object. When different forces act on an object, they can...
1.1K
pV-Diagrams01:18

pV-Diagrams

4.1K
The pV diagram, which is a graph of pressure versus volume of the gas under study, is helpful in describing certain aspects of the substance. When the substance behaves like an ideal gas, the ideal gas equation describes the relationship between its pressure and volume. On a pV diagram, it is common to plot an isotherm, which is a curve showing p as a function of V with the number of molecules and the temperature fixed. Then, for an ideal gas, the product of the pressure of the gas and its...
4.1K
Isothermal Processes01:21

Isothermal Processes

3.6K
A thermodynamic process that occurs at constant temperature is called an isothermal process. Heat slowly flows into the system or out of the system to maintain thermal equilibrium. Processes involving phase changes like water evaporation into steam or freezing water into ice at a constant temperature are examples of Isothermal Processes.
An ideal gas can also undergo isothermal expansion or compression.
For example, consider 1 mole of an ideal gas inside an isolated cylinder at initial volume V...
3.6K
Kinetic Theory of an Ideal Gas01:12

Kinetic Theory of an Ideal Gas

3.5K
A mole is defined as the amount of any substance that contains as many molecules as there are atoms in exactly 12 grams of carbon-12. An Italian scientist Amedeo Avogadro (1776–1856) formed the  hypothesis that equal volumes of gas at equal pressure and temperature contain equal numbers of molecules, independent of the type of gas. Later, the hypothesis was developed to form the SI unit for measuring the amount of any substance.
The number of molecules in one mole is called...
3.5K
Adiabatic Processes for an Ideal Gas01:18

Adiabatic Processes for an Ideal Gas

3.1K
When an ideal gas is compressed adiabatically, that is, without adding heat, work is done on it, and its temperature increases. In an adiabatic expansion, the gas does work, and its temperature drops. Adiabatic compressions actually occur in the cylinders of a car, where the compressions of the gas-air mixture take place so quickly that there is no time for the mixture to exchange heat with its environment. Nevertheless, because work is done on the mixture during the compression, its...
3.1K

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相关实验视频

Updated: Jun 23, 2025

Isotopic Effect in Double Proton Transfer Process of Porphycene Investigated by Enhanced QM/MM Method
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Isotopic Effect in Double Proton Transfer Process of Porphycene Investigated by Enhanced QM/MM Method

Published on: July 19, 2019

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在同位体组合中以同位体范式为基础.

Claudio A Cerdeiriña1, Jacobo Troncoso1

  • 1Instituto de Física e Ciencias Aeroespaciais da Universidade de Vigo and Unidad MSMN Asociada al CSIC por el IQF Blas Cabrera, 32004 Ourense, Spain.

Entropy (Basel, Switzerland)
|June 26, 2024
PubMed
概括
此摘要是机器生成的。

本综述探讨了可压缩电池模型,包括格子气体和液体,以了解流体的临界性和水的临界性.

关键词:
类似于Ising的模型在 NpT 和 μpT 组合中.不对称流体的临界值.可压缩的细胞可压缩的细胞.结 结 结 结 是一种局部热效应 局部热效应水的不同寻常的热力学.

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In Situ Monitoring of Diffusion of Guest Molecules in Porous Media Using Electron Paramagnetic Resonance Imaging
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Computation of Atmospheric Concentrations of Molecular Clusters from ab initio Thermochemistry
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Last Updated: Jun 23, 2025

Isotopic Effect in Double Proton Transfer Process of Porphycene Investigated by Enhanced QM/MM Method
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In Situ Monitoring of Diffusion of Guest Molecules in Porous Media Using Electron Paramagnetic Resonance Imaging
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Computation of Atmospheric Concentrations of Molecular Clusters from ab initio Thermochemistry
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科学领域:

  • 统计力学 统计力学
  • 热力学是一种热力学.
  • 材料科学 材料科学 材料科学

背景情况:

  • 使用NpT和μpT组合研究具有波动细胞体积的Ising类模型.
  • 在这些模型中,与体积现象一起,局部热效应至关重要.

研究的目的:

  • 审查最近对可压缩细胞模型的工作,包括可压缩细胞气体 (CCG) 和可压缩细胞液体 (CCL).
  • 探索它们在描述流体关键性,超冷水和液体-液体过渡中的应用.

主要方法:

  • 专注于具有波动体积的"可压缩细胞"的Ising类模型.
  • 在NpT和μpT组合中对可压缩细胞气体 (CCG) 和可压缩细胞液体 (CCL) 的分析.
  • 将"类似冰的"结合和空置细胞纳入模型.

主要成果:

  • CCG表现出单一的直径和"阳特征"从"完整的缩放"在不对称的流体关键性.
  • CCL变体作为类似水的液体-液体临界度和硬球结冰的原型.
  • 来自CCL的三态BEG类模型成功地描述了水的"第二关键点场景"和的相位行为.

结论:

  • 可压缩细胞模型为理解复杂的热力学现象提供了强大的框架.
  • 这些模型为水的不同寻常行为和简单物质的相变提供了洞察力.
  • 未来的研究应该解决水的水晶流体相行为和超稳定状态.