描述自然有机物 (NOM) 巨孔离子交换膜吸附剂的去除-吸附和再生行为
Jon Wullenweber1,2, Julia Bennert1, Tomi Mantel1
1Institute for Water Resources and Water Supply, Hamburg University of Technology, Am Schwarzenberg-Campus 3, 21073 Hamburg, Germany.
Membranes
|June 26, 2024
概括
两个离子交换膜有效地去除了用于水处理的自然有机物质 (NOM). 与Sartobind® D相比,Sartobind® Q显示出更好的再生和容量稳定性.
科学领域:
- 水处理技术水处理技术.
- 膜科学是一种科学.
- 环境化学环境化学
背景情况:
- 自然有机物 (NOM) 的去除对于饮用水安全至关重要.
- 消毒副产品前体通常与NOM.相关.
- 功能化的膜为先进的水净化提供了潜在的潜力.
研究的目的:
- 评估两种商用离子交换膜吸附器用于NOM去除.
- 为了比较四级胺 (Q) 和三级胺 (D) 的功能化膜的性能.
- 评估操作参数和再生对膜有效性的影响.
主要方法:
- 使用苏瓦尼河NOM (SRNOM) 作为替代品.
- 进行了兰迈尔吸附异热分析以确定吸附能力.
- 研究了不同pH值的流量变化和泽塔潜力.
- 通过NaOH再生进行了循环吸附-脱附实验.
主要成果:
- 这两种膜都显示出高的NOM吸附能力 (Qmax ≈ 2900 mg C/m2).
- 流量变化对突破时间的影响很小,这表明扩散限制很低.
- 在循环中,Sartobind® Q保持了容量和再生效率 (>99%).
- 萨托邦德® D需要酸性调节,以便在再生后恢复能力.
结论:
- 离子交换膜吸附剂在去除NOM和潜在的消毒副产品前体方面表现有前途.
- 在连续水处理应用中,Sartobind® Q具有更高的稳定性和可再生性.
- 膜吸附器技术最初用于生物技术,可以适应净化水的挑战.
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