在化LiCl-NaCl-KCl盐中20G和TP347H的腐蚀行为
Shijing Xie1, Min Lei1, Jiawei Sun1
1School of Nuclear Science and Technology, Xi'an Jiaotong University, Xi'an 710049, China.
Nanomaterials (Basel, Switzerland)
|June 26, 2024
概括
这项研究表明,奥氏体钢TP347H在化盐中比20G钢具有更好的耐腐蚀性. 表面氧化物形成在高温融盐环境中对这两种材料的腐蚀率产生重大影响.
科学领域:
- 材料科学 材料科学 材料科学
- 腐蚀工程 腐蚀工程
- 高温电化学 高温电化学
背景情况:
- 化盐对先进的核反应堆来说是有前途的.
- 了解这些盐中的材料腐蚀对于安全性和寿命至关重要.
- 20G和TP347H钢是高温应用的候选材料.
研究的目的:
- 为了研究和比较20G和TP347H钢在化LiCl-NaCl-KCl盐中的腐蚀行为.
- 确定影响腐蚀速率的关键因素,例如表面氧化物形成.
- 评估奥氏体钢中颗粒间腐蚀的可能性.
主要方法:
- 对20G和TP347H在化LiCl-NaCl-KCl中的材料测试.
- 对表面氧化物层和腐蚀产物的分析.
- 微观结构检查以确定腐蚀机制.
主要成果:
- 20G和TP347H都在化盐中经历了较高的腐蚀率.
- 与20G钢相比,TP347H钢具有更高的耐腐蚀性.
- 在这两种材料的腐蚀过程中,表面氧化物形成起到了至关重要的作用.
- 由于与氧化物和合金的化物离子反应,在TP347H中观察到晶体间腐蚀.
结论:
- 奥氏体钢TP347H在化盐中表现比20G钢更好.
- 保护性氧化物层的形成是缓解腐蚀的关键.
- 需要进一步的研究来开发用于盐应用的耐腐蚀材料.
相关概念视频
Solubility Equilibria
52.5K
Solubility equilibria are established when the dissolution and precipitation of a solute species occur at equal rates. These equilibria underlie many natural and technological processes, ranging from tooth decay to water purification. An understanding of the factors affecting compound solubility is, therefore, essential to the effective management of these processes. This section applies previously introduced equilibrium concepts and tools to systems involving dissolution and precipitation.
The...
The...
52.5K
Factors Affecting Solubility
33.4K
Compared with pure water, the solubility of an ionic compound is less in aqueous solutions containing a common ion (one also produced by dissolution of the ionic compound). This is an example of a phenomenon known as the common ion effect, which is a consequence of the law of mass action that may be explained using Le Chȃtelier’s principle. Consider the dissolution of silver iodide:
33.4K
Chemical Reactions in Aqueous Solutions
60.5K
Chemical substances interact in many different ways. Certain chemical reactions exhibit common patterns of reactivity. Due to the vast number of chemical reactions, it becomes necessary to classify them based on the observed patterns of interaction.
60.5K
Determining the pH of Salt Solutions
43.5K
The pH of a salt solution is determined by its component anions and cations. Salts that contain pH-neutral anions and the hydronium ion-producing cations form a solution with a pH less than 7. For example, in ammonium nitrate (NH4NO3) solution, NO3− ions do not react with water whereas NH4+ ions produce the hydronium ions resulting in the acidic solution. In contrast, salts that contain pH-neutral cations and the hydroxide ion-producing anions form a solution with a pH greater than...
43.5K
Precipitation of Ions
27.9K
Predicting Precipitation
The equation that describes the equilibrium between solid calcium carbonate and its solvated ions is:
The equation that describes the equilibrium between solid calcium carbonate and its solvated ions is:
27.9K
Electrolysis
26.3K
In a galvanic cell, the electrical work is done by a redox system on its surroundings as electrons produced by the spontaneous redox reactions are transferred through an external circuit. Alternatively, an external circuit does work on a redox system by imposing a voltage sufficient to drive an otherwise nonspontaneous reaction in a process known as electrolysis. For instance, recharging a battery involves the use of an external power source to drive the spontaneous (discharge) cell reaction in...
26.3K


