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相关概念视频

Molecular and Ionic Solids02:54

Molecular and Ionic Solids

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Crystalline solids are divided into four types: molecular, ionic, metallic, and covalent network based on the type of constituent units and their interparticle interactions.
Molecular Solids
Molecular crystalline solids, such as ice, sucrose (table sugar), and iodine, are solids that are composed of neutral molecules as their constituent units. These molecules are held together by weak intermolecular forces such as London dispersion forces, dipole-dipole interactions, or hydrogen bonds, which...
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Ion Exchange01:17

Ion Exchange

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Ion exchange chromatography separates charged molecules from a solution by reversibly exchanging them with mobile, or 'active', ions associated with the oppositely charged stationary phase. This method can be used to separate ions, soften and deionize water, and purify solutions. The polymers comprising the ion-exchange column are high-molecular-weight and chemically stable polymers, crosslinked to be porous and essentially insoluble. They are also functionalized with either acidic or...
574
Electrolyte and Nonelectrolyte Solutions02:21

Electrolyte and Nonelectrolyte Solutions

62.7K
Substances that undergo either a physical or a chemical change in solution to yield ions that can conduct electricity are called electrolytes. If a substance yields ions in solution, that is, if the compound undergoes 100% dissociation, then the substance is a strong electrolyte. Complete dissociation is indicated by a single forward arrow. For example, water-soluble ionic compounds like sodium chloride dissociate into sodium cations and chloride anions in aqueous solution.
62.7K
Ionic Bonding and Electron Transfer02:48

Ionic Bonding and Electron Transfer

41.4K
Ions are atoms or molecules bearing an electrical charge. A cation (a positive ion) forms when a neutral atom loses one or more electrons from its valence shell, and an anion (a negative ion) forms when a neutral atom gains one or more electrons in its valence shell. Compounds composed of ions are called ionic compounds (or salts), and their constituent ions are held together by ionic bonds: electrostatic forces of attraction between oppositely charged cations and anions. 
41.4K
Ionic Bonds00:42

Ionic Bonds

118.2K
Overview
When atoms gain or lose electrons to achieve a more stable electron configuration they form ions. Ionic bonds are electrostatic attractions between ions with opposite charges. Ionic compounds are rigid and brittle when solid and may dissociate into their constituent ions in water. Covalent compounds, by contrast, remain intact unless a chemical reaction breaks them.
Opposing Charges Hold Ions Together in Ionic Compounds
Ionic bonds are reversible electrostatic interactions between ions...
118.2K
Ionic Crystal Structures02:42

Ionic Crystal Structures

14.3K
Ionic crystals consist of two or more different kinds of ions that usually have different sizes. The packing of these ions into a crystal structure is more complex than the packing of metal atoms that are the same size.
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
14.3K

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Synthesis of Ionic Liquid Based Electrolytes, Assembly of Li-ion Batteries, and Measurements of Performance at High Temperature
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作为电池的固体电解质的Piperazinium Poly ((离子液体)

Antonela Gallastegui1, Gabriele Lingua1, Naroa Lopez-Larrea1

  • 1POLYMAT, University of the Basque Country UPV/EHU, Avenida Tolosa 72, Donostia-San Sebastian, Gipuzkoa, 20018, Spain.

Macromolecular rapid communications
|June 26, 2024
PubMed
概括

新的多离子液体提供了有前途的储能解决方案. 这些皮佩拉聚合物电解质显示出高离子导电性和优异的金属兼容性,用于先进的电池.

关键词:
电池 电池 电池 电池 电池皮佩拉津 (Piperazine) 是一种制剂.管子金 (Piperazinium) 是一种这是一种多离子液体.固体电解质是一种固体电解质.

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科学领域:

  • 材料科学 材料科学 材料科学
  • 电化学 电化学 电化学
  • 聚合物化学 聚合物化学

背景情况:

  • 多离子液体将离子液体的特性整合到聚合物中,用于储能.
  • 离子液体 (IL) 为电化学应用提供了独特的特性.

研究的目的:

  • 合成和描述基于piperazinium单体的新型多离子液体.
  • 评估它们作为储能固体聚合物电解质的潜力.

主要方法:

  • 用硫胺离子 (TFSI,FSI) 合成化聚 (?? 烯胺) 的合成.
  • 聚合物电解质的特征及其与金属的兼容性.
  • 在不同温度下测量离子导电性.

主要成果:

  • 在100°C以pyrrolidonium ILs和LiFSI达到5×10−3 S cm−1的高离子导电性.
  • 在高电流密度和40°C时,证明了出色的可逆金属和剥离.

结论:

  • 基于piperazinium的多离子液体是有效的固体聚合物电解质.
  • 这些材料对高性能金属电池和储能器件具有显著的前景.