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表面梯度为离子电池的丰富阴极
Huan Chen1,2, Huihui Yuan1,2, Zhongqin Dai1,2
1The State Key Lab High-Performance Ceram & Superfine, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai, 200050, P. R. China.
Advanced materials (Deerfield Beach, Fla.)
|June 26, 2024
概括
一种新的渐变阴极材料 (M-NCM) 通过提高结构稳定性和减少容量损失来提高离子电池的性能. 这种可扩展的方法可以提高电池寿命和充电速度,用于下一代储能.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 富含的多层氧化物阴极材料LiNixCoyMnzO2 (NCM),为离子电池 (LIB) 提供高容量.
- 实际应用受到接口不稳定性,相位过渡和容量衰减的阻碍.
研究的目的:
- 开发一种简单,可扩展的方法来制备渐变阴极材料 (M-NCM),以提高结构稳定性和速率性能.
- 为解决LIBs的NCM阴极材料中的容量损失和接口问题.
主要方法:
- 一种简单可扩展的合成方法,利用Ni2+与氨的协调和KMnO的减少.
- 在现场构建NCM阴极中的梯度组合设计.
主要成果:
- M-NCM阴极表现出更好的结构稳定性,减轻了Li/Ni混合和寄生性表面反应.
- 在200个循环后实现了98.6%的容量保留,在15°C的充电速率下达到107.5mAhg-1的容量保留.
- 一个1.2Ah袋式电池表现出超过500个周期,只有8%的容量损失.
结论:
- 梯度组合设计对于稳定晶体结构和提高电化学性能至关重要.
- 这项工作提出了一个可行的策略,用于制造高性能LIB的先进渐变阴极材料.
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