揭示相变热储电解质的温度不敏感特征,用于安全的电池
Zicheng Luo1, Yulong He1, Jia Hui2
1School of Materials Science & Engineering, Beihang University, Beijing, 100191, China.
Small (Weinheim an der Bergstrasse, Germany)
|June 26, 2024
概括
一种新型的温度不敏感的电解质通过在热冲击期间吸收热量来提高离子电池的安全性. 这一进步提高了热滥用耐受性,这对于广泛的电池应用至关重要.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 离子电池 (LIB) 提供高能量密度,但面临安全挑战,特别是在热应力下.
- 热冲击可能导致危险的电池故障,限制LIB应用程序.
研究的目的:
- 开发一种温度不敏感的电解质 (TI-电解质),以提高LIBs的热滥用耐受性.
- 为了研究新型TI电解质的热和电化学特性.
主要方法:
- 合成的TI电解质使用了两个相变聚合物 (聚烯和聚乙烯甘醇) 与不同的点.
- 热性质的特征,包括热容量 (27.3 J g−1).
- 电化学性能通过使用Li干LFP全细胞和对称Li干Li细胞进行评估.
主要成果:
- 由于相位过渡,TI电解质显示出显著的热吸收能力.
- 使用TI电解质的LFP囊细胞显示,与传统液体电解质相比,在热冲击期间温度升高的延迟为3分钟.
- 对称的Li能量电池实现了超过600小时的稳定循环,Li能量电池LFP全电池在0.5°C下提供了142.7mAhg-1的容量.
结论:
- 开发的TI电解质有效地减轻了LIBs中的热风险.
- 这种方法为提高离子电池的安全性和可靠性提供了一个有希望的策略.
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