在流体界面上粗的体的悖论性行为
Md Anisur Rahman1, Peter J Beltramo1
1Department of Chemical Engineering, University of Massachusetts Amherst, Amherst, Massachusetts 01003, United States.
ACS applied materials & interfaces
|June 26, 2024
概括
矛盾的是,表面粗性会影响流体界面上的体粒子相互作用. 虽然增强了球体的变形,但它削弱了体的变形,为粒子表面工程提供了新的途径.
科学领域:
- 体和接口科学科学
- 材料科学是一种材料科学.
- 聚合物科学 聚合物科学
背景情况:
- 体颗粒通过强烈吸附来稳定接口,接触角度决定行为.
- 颗粒表面的粗或形状的异构性会导致波浪状的接触线,导致四极面界变形和毛细管相互作用.
研究的目的:
- 研究表面粗对球形和形聚合物合物的界面变形和毛细血管相互作用的矛盾影响.
- 了解表面粗度如何影响不同粒子形状的潮湿行为和毛细血管力.
主要方法:
- 合成的球形和圆形聚合物合物,具有可控的表面粗度,使用种子乳液聚合.
- 在空气-水接口的单个合体周围测量在现场的界面变形.
- 采用数值预测来分析界面变形和毛细血管相互作用.
主要成果:
- 表面粗性加强了球体中的四极变形,符合理论.
- 相反,表面粗削弱了圆体中的四极变形.
- 增加的粗性导致了更多的水友颗粒,并减少了两种形状的明显接触角.
- 数字预测证实,降低湿度解释了圆体的界面变形减少.
结论:
- 表面粗度对界面变形和毛细血管相互作用具有形状依赖的悖论性影响.
- 粒子表面工程可以调整毛细管的变形和相互作用,通过改变湿行为和毛细管结,特别是对不对称的粒子.
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