基于回收的环氧板的活性碳及其对甲基色的吸附
Wenfeng Zhu1, Jiacheng He2, Qianxi Wang2
1State Key Laboratory of Oil and Gas Equipment, Tubular Goods Research Institute, China National Petroleum Corporation, Xi'an 710077, China.
Polymers
|June 27, 2024
概括
从电子垃圾中丢弃的环氧树脂被转化为活性炭以进行甲基色吸附. 这种可持续的方法产生高吸附能力,通过废物回收利用提供环境和经济效益.
科学领域:
- 材料科学 材料科学 材料科学
- 环境化学环境化学
- 废物管理 废物管理
背景情况:
- 电子废物,特别是废弃的电路板,构成了一个重要的非可降解废物挑战.
- 环氧树脂是电路板的常见组成部分,是有价值材料的潜在前体.
研究的目的:
- 从废弃的环氧树脂中制备活性炭 (AC).
- 为了研究准备的AC对甲基色的吸附性能.
- 探索废物回收和经济效益的潜力.
主要方法:
- 使用逐步碳化和激活方法将环氧树脂转化为AC.
- 进行了吸附实验,以研究甲基色去除的动力学和同热量.
- 计算了热力学参数,包括变化.
主要成果:
- 准备好的AC呈现出粗的碳结构,具有石墨和无形特征以及含氧组.
- 吸附遵循了准二次运动模型,平衡吸附达到41.051 mg/g.
- 吸附等热量与兰迈尔模型保持一致,在不同温度下显示和吸附量为23.137,30.358和37.202 mg/g.
- 证实了内热物理吸附过程 (ΔH = 17.30 KJ/mol).
结论:
- 来自废物环氧树脂的活性炭是有效的甲基色去除.
- 这种方法为电子废物管理和资源回收提供了可持续的解决方案.
- 该过程显示出减少污染和产生经济价值的巨大潜力.
相关概念视频
Oxidations of Aldehydes and Ketones to Carboxylic Acids
Oxidation of aldehydes and ketones results in the formation of carboxylic acids. Aldehydes, bearing hydrogen next to the carbonyl group, are easily oxidized compared to ketones. This is because an aldehydic proton can easily be abstracted during oxidation.
Aldehydes readily undergo oxidation in strong oxidizing agents such as potassium permanganate and chromic acid. The oxidation can also be carried out using mild oxidizing agents such as silver oxide. In fact, aldehydes can be easily oxidized...
Aldehydes readily undergo oxidation in strong oxidizing agents such as potassium permanganate and chromic acid. The oxidation can also be carried out using mild oxidizing agents such as silver oxide. In fact, aldehydes can be easily oxidized...
Carboxylic Acids to Methylesters: Alkylation using Diazomethane
Carboxylic acids react with diazomethane in an ether solvent via alkylation at the carboxylate oxygen atom to give methyl esters of the corresponding acid with excellent yields.
Ion Exchange
Ion exchange chromatography separates charged molecules from a solution by reversibly exchanging them with mobile, or 'active', ions associated with the oppositely charged stationary phase. This method can be used to separate ions, soften and deionize water, and purify solutions. The polymers comprising the ion-exchange column are high-molecular-weight and chemically stable polymers, crosslinked to be porous and essentially insoluble. They are also functionalized with either acidic or basic...


