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Updated: Jun 22, 2025

Chemiluminescence-based Assays for Detection of Nitric Oxide and its Derivatives from Autoxidation and Nitrosated Compounds
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紫外线光驱动的氧化从多孔异环聚合物释放

Sharon T Gregg1, René-Ponce Nze1, Qingchun Yuan2

  • 1School of Chemistry and Chemical Engineering, Queen's University of Belfast, David Keir Building, Stranmillis Road, Belfast, BT9 5AG, UK.

Macromolecular rapid communications
|June 27, 2024
PubMed
概括

研究人员开发了新型多孔聚合物,能够根据需求储存和释放氧化 (NO). 紫外线光触发了这些富含的材料中受控的NO释放,显示了光疗应用的潜力.

关键词:
光照射辐射的光照射.氧化氧化是什么?化化化化化照相响应度 照相响应度有孔的聚合物聚合物.

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Nitrous acid is a relatively weak and unstable acid prepared in situ by the reaction of sodium nitrite and cold, dilute hydrochloric acid. In an acidic solution, the nitrous acid undergoes protonation when it loses water to form a nitrosonium ion—an electrophile. Nitrous acid reacts with primary amines to give diazonium salts. The reaction is called diazotization of primary amines.
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Nitrous acid and nitric acids are two types of acids containing nitrogen, among which nitrous acid is weaker than nitric acid. Nitrous acid with a pKa value of 3.37 ionizes in water to give a nitrite ion and the hydronium ion.
The nitrous acid is unstable. Hence, it is formed in situ from a solution of sodium nitrite and cold aqueous acids such as hydrochloric or sulfuric acid. In an acidic solution, the –OH group of nitrous acid undergoes protonation to give oxonium ion, followed by...
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