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Updated: Jun 22, 2025

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通过选择性依赖氧化酶的区域选择性化拉万杜亚宁

Jackson T Baumgartner1, Shaun M K McKinnie1

  • 1Department of Chemistry and Biochemistry, University of California, Santa Cruz, California 95064, United States.

Organic letters
|June 27, 2024
PubMed
概括

海洋活性菌产生具有抗生素特性的独特化酶. 研究人员发现了一种新型的氨酸化酶 (LvcH) 酶,对于它们的C2化是至关重要的,使化学酶合成成为可能.

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Arenediazonium substitution reactions occur when the diazonium group is substituted by various functional groups such as halides, hydroxyl, nitrile, etc. For instance, arenediazonium salts react with copper(I) salts of chloride, bromide, or cyanide to form corresponding aryl chlorides, bromides, and nitriles. These reactions are named Sandmeyer reactions. Although the mechanism of this reaction is complicated, as illustrated in Figure 1, they are believed to progress via an aryl copper...
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