可见到近红外的机械发光在双激活的脊柱体化合物中,用于多重信息反假冒
Zhicong Chen1, Peishan Shao1, Puxian Xiong1,2
1School of Physics and Optoelectronics; School of Materials Science and Engineering; Guangdong Provincial Key Laboratory of Fiber Laser Materials and Applied Techniques; Guangdong Engineering Technology Research and Development Center of Special Optical Fiber Materials and Devices; State Key Laboratory of Luminescent Materials and Devices, South China University of Technology, Guangzhou 510640, China.
ACS applied materials & interfaces
|June 27, 2024
概括
这项研究报告了一种新的可见到近红外机械发光 (ML) 材料,该材料是基于树脂激活的 spinel. 该材料表现出Bi3+到Bi2+的自我降解,可用于防伪和传感.
科学领域:
- 材料科学 材料科学 材料科学
- 固态物理 固态物理
- 发光的光度是非常的低.
背景情况:
- 机械发光 (ML) 将力转化为光,在传感和防伪方面有应用.
- 多价离子通过自我减少使多带ML成为可能,但木激活ML尚未得到充分探索.
研究的目的:
- 报告新型可见到近红外 (VIS-NIR) 的ML在斯木激活MgGa2O4.4.
- 研究Bi3+到Bi2+的自我降解机制及其在ML中的作用.
主要方法:
- 用斯穆特激活的旋转型MgGa2O4的合成.
- 光发光 (PL),PL激发 (PLE) 和PL生命周期光谱.
- 电子偏磁共振 (EPR) 和热发光 (TL) 光谱学.
主要成果:
- 在MgGa2O4:Bi中显示的NIR相对ML,归因于Bi3+/Bi2+发光中心.
- 提出了一种涉及空缺 (VMg′′) 和确认的氧空缺 (VO••) 的自我减少模型.
- 建立了一个由陷控制的ML机制,涉及电子孔对,并演示了双模式电子签名应用程序.
结论:
- 在MgGa2O4中,石自降是一种可行的对NIRML的可行途径.
- 开发的ML材料显示了防伪和多刺激响应应用的潜力.
- 这项工作为设计新型ML材料提供了见解.
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