在重新燃烧条件下研究NH3&CH4联合活性炭的相互作用
Yukai Li1, Shaozeng Sun2, Dongdong Feng2
1School of Energy Science and Engineering, Harbin Institute of Technology, Harbin 150001, China; Department of Mechanical Engineering, National University of Singapore, 9 Engineering Drive 1, Singapore 117575, Singapore.
将氨 (NH3) 和甲 (CH4) 添加到粉碎煤重新燃烧中,显著增加了氧化 (NO) 的减少. 这种混合物还可以改善煤炭燃烧.
科学领域:
- 环境科学 环境科学
- 化学工程是化学工程的重要组成部分.
- 燃烧科学 燃烧科学
背景情况:
- 越来越需要减少燃煤发电厂的温室气体排放.
- 煤炭再燃是减排的一个关键策略.
- 优化再燃效率对于可持续的能源生产至关重要.
研究的目的:
- 研究氨 (NH3) 和甲 (CH4) 联合燃烧对粉碎煤重新燃烧的影响.
- 评估对氧化 (NO) 减少和碳结构演变的影响.
- 了解增强再燃性能背后的机制.
主要方法:
- 使用平面火焰燃烧器来模拟重新燃烧区域的条件.
- 分析了煤炭的物理和化学结构变化.
- 量化氧化 (NO) 减少潜力与NH3 / CH4的添加.
- 测量了BET特定表面积和毛孔体积的变化.
主要成果:
- 与回流烟气相比,NH3/CH4混合显著增加了约0.67倍的NO减少.
- NH3促进了C=O债券的转换,增强了NO的减少.
- 特定于BET的表面积增加了50%,毛孔总体积增加了21.43%.
- 查尔表面的化学成分从N-Q转移到N-5和N-6物种.
结论:
- 同时燃烧NH3和CH4与粉碎煤是一种有前途的再燃技术.
- 这种方法优化了燃烧性能,并大大提高了NO减少.
- 该技术为减少发电厂二氧化碳和氧化排放提供了可行的途径.
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