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马尔托斯添加剂使离子的压缩沉积成为可能,以稳定阳极
Huan Liu1, Hong Deng1, Shanshan Liu1
1School of Flexible Electronics (Future Technologies), Institute of Advanced Materials (IAM), Nanjing Tech University (NanjingTech), 30 South Puzhu Road, Nanjing 211816, China.
ACS applied materials & interfaces
|June 28, 2024
概括
马尔托斯添加剂通过防止树脂和腐蚀来提高水性离子电池的安全性. 这种功能添加剂促进了均的沉积,提高了电池循环稳定性和性能.
科学领域:
- 电化学 电化学 电化学
- 材料科学 材料科学 材料科学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 水性离子电池 (AZIB) 提供安全和经济高效的能源存储.
- 挑战包括阳极树突的生长,腐蚀和演化反应 (HER).
研究的目的:
- 研究马尔托 (MT) 作为一种电解质添加剂,用于保护AZIB中的金属阳极.
- 为了抑制HER和腐蚀,同时促进均的沉积.
主要方法:
- 使用麦芽糖作为功能性电解质添加剂.
- 分析其对金属接口和沉积行为的影响.
- 测试对称和完整的细胞 (Zn下载者NH4V4O10).
主要成果:
- 马尔托斯有效地抑制了HER和阳极的腐蚀反应.
- 它通过促进稳定的 (100) 晶体平面来诱导均的沉积.
- 对称细胞实现了2000小时的稳定循环;全细胞维持了1000个循环.
结论:
- 马尔托斯是一种有前途的添加剂,可以提高AZIB的稳定性和性能.
- 这种方法提供了一个可行的策略,以实现统一的沉积和减轻阳极问题.
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