一种被动活性抗/脱冰涂层,集成超性,隔热和光/电热转换效应
Huan Wei1, Haihang Luo1, Weiwei Fan1
1National Engineering Research Center of Clean Technology in Leather Industry, Sichuan University, Chengdu 610065, P. R. China.
ACS applied materials & interfaces
|July 1, 2024
概括
这项研究开发了一种使用硫化铜激活生物炭的耐用抗结冰涂层. 该涂层通过结合超性,隔热和光电热效应来提供出色的被动和活性防冰,以有效地防止和去除冰.
科学领域:
- 材料科学 材料科学 材料科学
- 表面化学 表面化学
- 纳米技术纳米技术
背景情况:
- 防/脱冰涂层对于防止冰形成至关重要.
- 现有的涂层在热量损失和低效的能量转换方面扎.
- 结合主动和被动方法提供了一个有希望的方法.
研究的目的:
- 开发一个具有增强性能的集成抗/脱冰涂层.
- 研究超性,热绝缘和光电热性质的协同效应.
- 为了评估涂层在各种环境条件下的耐用性.
主要方法:
- 使用硫化铜加载活性生物炭 (AC@CuS),聚二甲基和可扩展微球来制造涂层.
- 通过测量水滴结时间来表征被动抗结冰特性.
- 在不同功率密度下使用光电热效应评估活性脱冰性能.
- 通过机械,环境和化学应力测试来评估涂层的耐用性.
主要成果:
- 涂层显示水滴冷时间显著延长 (150到2140秒),表明优越的被动抗结冰.
- AC@CuS 实现了高效的光电热转换,温度达到 96.4 摄氏度 (电) 和 113 摄氏度 (光).
- 协同加热在2.5分钟内迅速融化了冰.
- 在经过广泛的耐久性测试后,该涂层保持了超性 (WCA > 150°).
结论:
- 开发的涂层有效地整合了被动和主动的抗/脱冰机制.
- 协同效应增强了抗结冰和脱冰能力.
- 涂层具有出色的耐用性,确保在恶劣条件下长期性能.
相关概念视频
Radiation: Applications
The average temperature of Earth is the subject of much current discussion. Earth is in radiative contact with both the Sun and dark space; it receives almost all its energy from the radiation of the Sun and reflects some of it into outer space. Dark space is very cold, about 3 K, so Earth radiates energy into it. For instance, heat transfer occurs from soil and grasses, the rate of which can be so rapid that frost can occur on clear summer evenings, even in warm latitudes.
The average...
The average...
Colloidal precipitates
The high insolubility of some precipitates can result in an unfavorable relative supersaturation. This can lead to colloidal particles with a large surface-to-mass ratio, where adsorption is promoted. For instance, in the precipitation of silver chloride, silver ions are adsorbed on the surface of the colloidal particles, forming a primary layer. This layer attracts ions of opposite charge (such as nitrate ions), forming a diffuse secondary layer of adsorbed ions. This electric double layer...
The Electrical Double Layer
In the region where two bulk phases meet, an intricate electric charge distribution arises due to charge transfer, ion adsorption, molecular orientation, and charge distortion. This complex distribution is commonly referred to as the electrical double layer.When a solid electrode interfaces with ions in an electrolyte solution, the speed of electron transfer dictates the rates of oxidation and reduction. The electrode acquires a charge through the escape of atoms into the solution as cations or...
Surface Active Agents
Surfactants, named for their behavior at interfaces, positively adsorb at the interfaces of two phases, reducing interfacial tension. Their versatility as emulsifiers, detergents, and foaming agents stems from this ability. Surfactants, often termed amphiphiles, share the property of amphipathy, with molecules having both hydrophilic and hydrophobic portions. The hydrophilic part is called the head, and the hydrophobic part, including an elongated alkyl substituent, forms the tail.Surfactants...
Frost Action on Concrete
Concrete structures in cold climates, such as those along roadsides, can retain moisture. This moisture makes them susceptible to frost-related damage when temperatures fall below freezing. Adding moisture worsens the damage during temperature fluctuations, leading to repeated freezing and thawing. De-icing salts, spread over these structures to melt ice, add to the freeze-thaw cycle, and draw even more moisture into the concrete.
This freeze-thaw cycle primarily causes surface scaling, where...
This freeze-thaw cycle primarily causes surface scaling, where...
Frost Resistant Concrete
Concrete's susceptibility to frost damage during freeze-thaw cycles demands strategic measures to enhance its frost resistance. Employing techniques like air entrainment, adjusting the water-cement ratio, proper curing, and selecting appropriate aggregates are essential.
Introducing microscopic air bubbles into the concrete mix through air entrainment creates small voids that accommodate ice expansion, thereby reducing internal pressures and preventing cracking. The optimal amount of entrained...
Introducing microscopic air bubbles into the concrete mix through air entrainment creates small voids that accommodate ice expansion, thereby reducing internal pressures and preventing cracking. The optimal amount of entrained...


