相关实验视频

Updated: Jun 22, 2025

Highly Stereoselective Synthesis of 1,6-Ketoesters Mediated by Ionic Liquids: A Three-component Reaction Enabling Rapid Access to a New Class of Low Molecular Weight Gelators
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Highly Stereoselective Synthesis of 1,6-Ketoesters Mediated by Ionic Liquids: A Three-component Reaction Enabling Rapid Access to a New Class of Low Molecular Weight Gelators

Published on: November 27, 2015

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β-环极素-NHC-Au(I) -催化化 1,5-烯环异构化

Mehdi Koohgard1, Lukas Enders1,2, Natalia Del Rio1

  • 1Sorbonne Université, CNRS, Institut Parisien de Chimie Moléculaire, 4 place Jussieu, 75005 Paris, France.

Organic letters
|July 1, 2024
PubMed
概括

这项研究表明,使用空腔驱动的催化方法,高合性黄金 (((I) 催化循环异构化. 这种方法有效地将埃尼因,埃尼诺和埃尼尼埃斯特的种族混合物转化为光学活性产品.

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Catalytic hydrogenation of alkenes is a transition-metal catalyzed reduction of the double bond using molecular hydrogen to give alkanes. The mode of hydrogen addition follows syn stereochemistry.
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