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Updated: Jun 22, 2025

Synthesis of Antiviral Tetrahydrocarbazole Derivatives by Photochemical and Acid-catalyzed C-H Functionalization via Intermediate Peroxides CHIPS
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1,3,4-氧化和胺酸衍生物的可见光驱动合

Shiyun He1, Xingyu Liu1, Guanghui Lv1,2

  • 1Key Laboratory of Drug-Targeting and Drug Delivery System of the Education Ministry and Department of Medicinal Chemistry, Sichuan Engineering Laboratory for Plant-Sourced Drug and Sichuan Research Center for Drug Precision Industrial Technology, West China School of Pharmacy, Sichuan University, No. 17 Southern Renmin Road, Chengdu, Sichuan 610041, People's Republic of China.

The Journal of organic chemistry
|July 2, 2024
PubMed
概括

一种新的可见光驱动交叉合反应使得5-aryl-1,3,4-oxadiazole-2-methylamines的合成成为可能. 这种无金属和无基的方法为有价值的化合物提供了广泛的范围和高的功能组耐受性.

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The reaction of weakly electrophilic aryldiazonium (also called arenediazonium) salts with highly activated aromatic compounds leads to the formation of products with an —N=N— link, called an azo linkage. This reaction, presented in Figure 1, is known as diazo coupling and occurs without the loss of the nitrogen atoms of the aryldiazonium salt. Highly activated aromatic compounds such as phenols or arylamines favor the diazo coupling reaction. The coupling generally occurs at the...
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