大气中的H2O2在中国大城市的雾期间:度,来源和对硫酸盐生产的影响
Yunxiang Zhang1, Shenbo Wang1, Panru Kang2
1Research Institute of Environmental Sciences, Zhengzhou University, Zhengzhou 450000, China; School of Ecology and Environment, Zhengzhou University, Zhengzhou 450000, China.
The Science of the total environment
|July 2, 2024
概括
在中国州重度污染期间,发现大气中过氧化 (H2O2) 的含量较高. 这一令人惊的发现是由粒子相反应和生物质燃烧驱动的,影响了硫酸盐形成过程.
科学领域:
- 大气化学 大气化学
- 空气污染研究研究
- 环境科学 环境科学
背景情况:
- 大气中的过氧化 (H2O2) 是大气化学中的关键氧化剂.
- 了解污染的城市环境中的H2O2行为对于空气质量管理至关重要.
- 之前的研究还没有完全阐明重污染事件期间的H2O2度.
研究的目的:
- 调查大气H2O2的特征和度在一个受污染的地区 (州,中国).
- 为了比较H2O2水平和重污染 (HP) 和轻污染 (LP) 日之间的影响因素.
- 评估H2O2在不同污染情景中的硫酸盐形成途径中的作用.
主要方法:
- 在2019年2月22日至3月4日在州进行了全面的大气观测.
- 在重污染 (HP) 和轻污染 (LP) 之间进行不同的测量.
- 分析了H2O2,NO和其他相关大气参数的度.
主要成果:
- 较高的H2O2度 (1.5 ± 0.6 ppbv) 在HP日观察到与LP日 (1.2 ± 0.6 ppbv) 相比.
- 在HP中增加的H2O2与低风速,高相对湿度,加剧的粒子相光反应和生物质燃烧有关.
- H2O2的氧化率显著增加,从LP中的3.6 × 10^-2增加到HP中的1.1 × 10^-1 μg m^-3 h^-1.
结论:
- 与预期相反,州的严重污染条件导致大气H2O2度增加.
- 过渡金属离子 (TMI) 催化氧化是主要的硫酸盐形成途径,但H2O2氧化在HP期间变得显著.
- 在特定条件下,H2O2氧化可以超过TMI催化,成为污染大气中硫酸盐形成的主要驱动因素.
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