电催化剂将水转化为氧化物:通过氧化还原介导对直接转移氧气
Bing-Liang Leng1, Xiu Lin1, Jie-Sheng Chen1
1School of Chemistry and Chemical Engineering, Frontiers Science Center for Transformative Molecules, Shanghai Jiao Tong University, Shanghai, 200240, P. R. China. xinhaoli@sjtu.edu.cn.
概括
这项研究探讨了用水作为可持续化学生产的氧气来源的电催化氧化. 它详细介绍了有效的氧气转移策略,重点关注更清洁的合成直接方法.
科学领域:
- 电化学 电化学 电化学
- 可持续化学 可持续化学
- 催化剂是一种催化剂.
背景情况:
- 电催化氧化提供了可持续的氧化化合物的生产和减少排放.
- 在电催化中利用水作为氧气来源,降低了环境和能源成本.
- 氧物种的生成和转化对于氧化反应的效率至关重要.
研究的目的:
- 为了阐明电催化氧化中的氧气转移过程.
- 详细介绍催化剂设计策略,以便在阳极有效地直接转移氧气.
- 为了探索超越氧气转移的更绿色的有机合成.
主要方法:
- 对氧化还原介导和直接氧气转移途径的审查.
- 对有机基质激活,氧物种管理和产品转化催化剂设计的分析.
- 研究用于有机激活的电子转移加速.
主要成果:
- 突出的是阳极的直接氧气传递机制.
- 有效的氧气转移策略包括平衡氧气物种生成/转化,调整基质/中间体,加快电子转移.
- 催化剂设计对于优化这些过程至关重要.
结论:
- 有效的电催化氧化需要仔细管理氧气转移动态.
- 直接的氧气转移为可持续的有机合成提供了有希望的途径.
- 未来的研究可能会扩展到对原子和分子碎片的转移,以获得更绿色的化学.
相关概念视频
Electrolysis
26.3K
In a galvanic cell, the electrical work is done by a redox system on its surroundings as electrons produced by the spontaneous redox reactions are transferred through an external circuit. Alternatively, an external circuit does work on a redox system by imposing a voltage sufficient to drive an otherwise nonspontaneous reaction in a process known as electrolysis. For instance, recharging a battery involves the use of an external power source to drive the spontaneous (discharge) cell reaction in...
26.3K
Redox Equilibria: Overview
558
A reduction-oxidation reaction is commonly called a redox reaction. In a redox reaction, electrons are transferred from one species to another rather than being shared between or among atoms. The reducing agent or reductant is the species that loses electrons and gets oxidized in the process. The species that gains electrons and gets reduced in the process is the oxidizing agent or oxidant. Redox reactions are represented as two separate equations called half-reactions, where one equation...
558
Balancing Redox Equations
52.0K
Electrochemistry is the science involved in the interconversion of electrical and chemical reactions. Such reactions are called reduction-oxidation, or redox reactions. These important reactions are defined by changes in oxidation states for one or more reactant elements and include a subset of reactions involving the transfer of electrons between reactant species. Electrochemistry as a field has evolved to yield sufficient insights on the fundamental principles of redox chemistry and multiple...
52.0K
Oxidation-Reduction Reactions
64.7K
Oxidation–Reduction Reactions
64.7K
Batteries and Fuel Cells
27.3K
A battery is a galvanic cell that is used as a source of electrical power for specific applications. Modern batteries exist in a multitude of forms to accommodate various applications, from tiny button batteries such as those that power wristwatches to the very large batteries used to supply backup energy to municipal power grids. Some batteries are designed for single-use applications and cannot be recharged (primary cells), while others are based on conveniently reversible cell reactions that...
27.3K
Oxidation and Reduction of Organic Molecules
6.4K
Energy production within a cell involves many coordinated chemical pathways. Most of these pathways are combinations of oxidation and reduction reactions, which occur at the same time. An oxidation reaction strips an electron from an atom in a compound, and the addition of this electron to another compound is a reduction reaction. Because oxidation and reduction usually occur together, these pairs of reactions are called redox reactions.
The removal of an electron from a molecule, results in a...
The removal of an electron from a molecule, results in a...
6.4K


