工业人类及其分量的分子结构和组成的阐明
Sandra Constant1,2, Christopher S Lancefield1, Willem Vogelzang3
1Inorganic Chemistry and Catalysis, Institute for Sustainable and Circular Chemistry and Debye Institute for Nanomaterials Science, Faculty of Science, Utrecht University Universiteitsweg 99 3584 CG Utrecht The Netherlands p.c.a.bruijnincx@uu.nl.
概括
这项研究详细介绍了工业人体的结构,这是碳水化合物脱水的副产品. 与实验室模型不同,这些人体具有较低的交叉连接和更高的功能,提供新的价值化途径.
科学领域:
- 生物提炼和碳水化合物化学.
- 材料科学和聚合物表征.
背景情况:
- 人类是生物提炼中碳水化合物脱水的副产品.
- 目前的知识依赖于实验室规模的合成人体,而不是工业化的人体.
研究的目的:
- 进行首次对工业人类进行广泛的表征.
- 了解来自Avantium YXY®工艺的人体结构和组成.
- 识别工业人类潜在的价值化机会.
主要方法:
- 工业人体的分离和分离成不溶于水 (WIPIH) 和溶于水 (WES) 的部分.
- 使用元素分析,热重力测量,IR,NMR光谱和尺寸排除色谱进行表征.
- 利用化合物的NMR光谱库进行结构阐明.
主要成果:
- 详细的结构和组成分析 WIPIH 和 WES 分数.
- 识别 furan 构成块和单位间的联系.
- 鉴定结果显示,环由有形链连接在一起,具有多种功能组 (酒精,,酸,,化物,).
结论:
- 与合成模型相比,工业人体呈现较低的交叉连接和更高的功能组含量.
- 这些人类可以被认为是简单类和高度凝聚的人类之间的中间体.
- 结构洞察力为各种工业价值化应用铺平了道路.
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