福尔塞拉兰:度,风学性质和结构对冰再结晶抑制活动的影响
Julian Gerhäuser1, Julia Hale2, Daniel Wefers3
1Institute of Process Engineering in Life Sciences, Food Process Engineering, Karlsruhe Institute of Technology, Kaiserstraße 12, 76131 Karlsruhe, Germany.
弗塞拉兰在冷储存期间有效地抑制冰晶的生长,类似于 κ-carrageenan. 然而,其在较高度下类似凝的稳定性会降低这种保护作用,这表明最佳使用需要避免凝形成.
科学领域:
- 生物物理学的生物物理.
- 材料科学 材料科学 材料科学
- 食品科学 食品科学 食品科学
背景情况:
- 重结晶是冷生物材料损坏的主要原因.
- 众所周知,诸如 κ-carrageenan 等多糖类可以抑制冰晶的生长.
- 相关的多糖化合物furcellaran因其冷保护性质而受到研究.
研究的目的:
- 评估furcellaran对冰晶生长和再结晶的度依赖作用.
- 为了描述furcellaran的结构,硫酸盐含量和质性质.
- 为了确定furcellaran的再结晶抑制活性的最佳条件.
主要方法:
- H核磁共振光谱仪用于结构分析.
- 离子染色学和高性能尺寸排除染色学用于硫酸盐含量和分子量测定.
- 风病学测量以评估不同度的furcellaran溶液的性能.
主要成果:
- 福尔塞拉兰显示出与 κ-carrageenan 相似的冰的增长抑制.
- 随着furcellaran度的增加,导致5g/L的凝状状态.
- 这种凝形成与减少再结晶抑制和更大的冰晶相关.
结论:
- 福尔塞拉兰是一种强大的冰的增长抑制剂,提供类似于 κ-carrageenan 的冷保护.
- 通过furcellaran实现最佳的再结晶抑制,其度低于诱导凝形成的度.
- 避免凝状的一致性对于最大限度地提高furcellaran在冷储存期间保存生物材料的有效性至关重要.
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