用于采矿的PVA/CMC/凝复合物的制备和风湿学特性
Xiaonan Shi1, Baiqian Wu2, Xuechao Dong2
1School of Statistics and Data Science, Qufu Normal University, Qufu, Shandong 273165, China.
ACS omega
|July 8, 2024
概括
这项研究优化了用于goaf填充的聚乙醇/碳甲基纤维素/凝 (PVA/CMC/Gel) 复合凝. 最佳的凝配方表现出伪塑性流体行为和高效的扩散沿着goaf dips.
科学领域:
- 材料科学 材料科学 材料科学
- 化学工程是化学工程的重要组成部分.
- 采矿工程 采矿工程 采矿工程
背景情况:
- 具有相互穿透网络的复合凝材料对于诸如填充等应用至关重要.
- 了解这些凝的风湿性质和扩散特性对于优化其性能至关重要.
研究的目的:
- 开发和表征一个聚乙烯醇/碳甲基纤维素/凝 (PVA/CMC/Gel) 复合凝用于填充.
- 为了确定复合物凝的最佳组成和质性质.
- 为了研究凝在模拟的GOAF环境中的透扩散行为.
主要方法:
- 化学交叉链接以形成复合凝.
- 粘度测量用于测量粘度,屈服应力和厚度变异.
- 对前线轨道能量进行计算分析,以评估凝剂与交联剂的相互作用.
- 数字模拟研究漏扩散在一个goaf.
主要成果:
- 该PVA/CMC/Gel复合凝表现出剪切稀释行为,按照功率定律模型作为伪塑性流体.
- 确定了30°C的最佳复合凝比率,包括凝剂,交联剂,碳化物渣,酒精氨基溶液和发泡剂的特定百分比.
- 凝与交联剂的反应性最强,而PVA的分子稳定性更高.
- 复合凝在模拟的4°浸入角和40分钟注射时间的模拟中优先沿着浸入扩散.
结论:
- 优化的PVA/CMC/Gel复合凝具有在煤矿中管道运输所需的可取的质性质.
- 这项研究提供了对复合凝在高环境中的扩散流的宝贵见解.
- 这项研究对煤矿填充材料的设计和了解地下流体动力学具有重要意义.
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