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Updated: Jun 21, 2025

Cercosporin-Photocatalyzed [4+1]- and [4+2]-Annulations of Azoalkenes Under Mild Conditions
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Published on: July 17, 2020

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多样化光酶的化学进化对整个细胞的反选择性 [2 + 2] 循环添加

Juan Guo1, Junyi Qian2, Daihong Cai1

  • 1Hubei Key Laboratory of Bioinorganic Chemistry & Materia Medica, Hubei Engineering Research Center for Biomaterials and Medical Protective Materials, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology (HUST), 1037 Luoyu Road, Wuhan 430074, China.

Journal of the American Chemical Society
|July 8, 2024
PubMed
概括

研究人员开发了一种用于生物催化物的新方法. 这些新型酶有效地使用可见光进行具有挑战性的化学反应,扩大立体选择性转换的可能性.

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Some cycloaddition reactions are activated by heat, while others are initiated by light. For example, a [2 + 2] cycloaddition between two ethylene molecules occurs only in the presence of light. It is photochemically allowed but thermally forbidden.
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