在非化过程中利用酸盐和酸盐去除:电子受体偏好和可行的工艺组合
Ruimiao Zhang1, Junguo He2, Mengfei Wang1
1School of Environment, Harbin Institute of Technology, Harbin 150090, Heilongjiang, PR China; State Key Laboratory of Urban Water Resources and Environment, Harbin Institute of Technology, Harbin 150090, Heilongjiang, PR China.
Bioresource technology
|July 8, 2024
概括
无化除 (DPR) 污泥中含有更喜欢酸盐而不是酸盐的有机体. 这项研究澄清了DPR系统中化聚酸盐积聚生物体 (DPAO) 的脱能力.
科学领域:
- 环境微生物学环境微生物学
- 废水处理技术 废水处理技术
- 生物地质化学循环是什么
背景情况:
- 脱除 (DPR) 对于从废水中去除和至关重要.
- 脱聚酸盐积聚生物 (DPAOs) 主导着DPR,但它们的脱能力往往被共存的脱聚酸盐积聚生物 (DGAOs) 掩盖.
- 了解DPAO的特定脱能力对于优化DPR流程至关重要.
研究的目的:
- 在不同的气条件下 (酸盐与酸盐) 评估DPAO的脱能力.
- 调查DGAO丰富度对DPR污泥中DPAO脱的影响.
- 为了确定DPAO脱的首选电子受体.
主要方法:
- 在单独的反应堆中培养酸盐DPR和酸盐DPR污泥.
- 在无氧阶段用酸盐和酸盐操纵养策略.
- 对DGAO丰度的分析和脱率的评估 (酸盐和酸盐的减少).
主要成果:
- 与酸盐-DPR污泥中的酸盐减少率相比,DPAO的酸盐减少率 (1.63倍) 显著更高.
- 在化物-DPR污泥中,化物降解率是化物降解率的三倍以上,不管DGAO的丰度如何.
- 这些结果证实了DPAO对酸盐作为电子受体的偏好.
结论:
- DPAOs表现出强烈的偏好使用化物而不是酸盐进行脱化.
- DPAO在减少化物方面比化物更有效,这表明它在DPR系统中的化物供应中发挥了作用.
- 优化DPR过程可能涉及管理物种,以有利于酸盐可用性,以提高DPAO活性.
相关概念视频
Overview of Nitrogen Metabolism
7.9K
Nitrogen is a very important element for life because it is a major constituent of proteins and nucleic acids. It is a macronutrient, and in nature, it is recycled from organic compounds and stored in the form of ammonia, ammonium ions, nitrate, nitrite, or nitrogen gas by many metabolic processes. Many of these metabolic processes are carried out only by prokaryotes.
The largest pool of nitrogen available in the terrestrial ecosystem is gaseous nitrogen (N2) from the air, but this...
The largest pool of nitrogen available in the terrestrial ecosystem is gaseous nitrogen (N2) from the air, but this...
7.9K
2° Amines to N-Nitrosamines: Reaction with NaNO2
4.2K
Secondary amines react with nitrous acid to form N-nitrosamines, as depicted in Figure 1. Nitrous acid, a weak and unstable acid, is formed in situ from an aqueous solution of sodium nitrite and strong acids, such as hydrochloric acid or sulfuric acid, in cold conditions. In the presence of an acid, the nitrous acid gets protonated. The subsequent loss of water results in the formation of the electrophile known as nitrosonium ion.
4.2K
The Nitrogen Cycle
51.9K
Nitrogen atoms, present in all proteins and DNA, are recycled between abiotic and biotic components of the ecosystem. However, the primary form of nitrogen on Earth is nitrogen gas, which cannot be used by most animals and plants. Thus, nitrogen gas must first be converted into a usable form by nitrogen-fixing bacteria before it can be cycled through other living organisms. The use of nitrogen-containing fertilizers and animal waste products in human agriculture has greatly influenced the...
51.9K
The Phosphorus Cycle
36.7K
Unlike carbon, water, and nitrogen, phosphorus is not present in the atmosphere as a gas. Instead, most phosphorus in the ecosystem exists as compounds, such as phosphate ions (PO43-), found in soil, water, sediment and rocks. Phosphorus is often a limiting nutrient (i.e., in short supply). Consequently, phosphorus is added to most agricultural fertilizers, which can cause environmental problems related to runoff in aquatic ecosystems.
36.7K
1° Amines to Diazonium or Aryldiazonium Salts: Diazotization with NaNO2 Overview
3.3K
Nitrous acid and nitric acids are two types of acids containing nitrogen, among which nitrous acid is weaker than nitric acid. Nitrous acid with a pKa value of 3.37 ionizes in water to give a nitrite ion and the hydronium ion.
The nitrous acid is unstable. Hence, it is formed in situ from a solution of sodium nitrite and cold aqueous acids such as hydrochloric or sulfuric acid. In an acidic solution, the –OH group of nitrous acid undergoes protonation to give oxonium ion, followed by...
The nitrous acid is unstable. Hence, it is formed in situ from a solution of sodium nitrite and cold aqueous acids such as hydrochloric or sulfuric acid. In an acidic solution, the –OH group of nitrous acid undergoes protonation to give oxonium ion, followed by...
3.3K
1° Amines to Diazonium or Aryldiazonium Salts: Diazotization with NaNO2 Mechanism
3.8K
Nitrous acid is a relatively weak and unstable acid prepared in situ by the reaction of sodium nitrite and cold, dilute hydrochloric acid. In an acidic solution, the nitrous acid undergoes protonation when it loses water to form a nitrosonium ion—an electrophile. Nitrous acid reacts with primary amines to give diazonium salts. The reaction is called diazotization of primary amines.
3.8K


