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Updated: Jun 21, 2025

Metal-free Synthesis of Ynones from Acyl Chlorides and Potassium Alkynyltrifluoroborate Salts
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通过发达的Ynol-diene循环,对17-nor-CephalotaneDiterpenoids进行不同的合成

Zezhong Sun1, Xin Shu1, Fuli Ma1

  • 1Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education, College of Chemistry & Materials Science, Northwest University, Xi'an, 710127, China.

Angewandte Chemie (International ed. in English)
|July 9, 2024
PubMed
概括

一种新的循环化策略使得17-nor-cephalotane diterpenoids的第一个分离合成成为可能. 这种方法成功地以简洁的方式生产了几种复杂的天然产品,包括 (+) - 哈林诺利德.

关键词:
生物模拟合成生物模拟合成不同的合成分离.自然产品是自然产品的产品.总合成总合成伊诺尔 - 迪因循环化

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