抑制溶解策略,在海水式双离子电池中实现高性能酸混合阳极
Siying Gou1, Xueying Zhang1, Yuanhu Xu1
1Guangxi Key Laboratory of Electrochemical and Magneto-chemical Functional Materials, Guangxi Key Laboratory of surface and interface electrochemistry, Department of Chemistry and Biological Engineering, Guilin University of Technology, Guilin 541004, China.
Journal of colloid and interface science
|July 9, 2024
概括
研究人员为水性离子电池开发了一种甲涂层酸碳纤维阳极. 这项创新提高了稳定性和容量,为储存阳极创造了新纪录.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 水性离子电池 (ASIB) 对大规模储能充满希望.
- 阳极的局限性,包括溶解和进化,阻碍了ASIB的性能.
研究的目的:
- 为ASIBs开发一个稳定,高容量的阳极.
- 为了克服酸 (NTP) 阳极的溶解问题.
主要方法:
- 制造一个酸-碳纤维 (NTP-CFs/Bi) 阳极.
- 在ASIB中电极性能的电化学表征.
- 组装和测试基于海水的ASIB电池.
主要成果:
- 双涂层有效地抑制了氧离子丰富,防止了NTP溶解.
- 该NTP-CFs/Bi阳极在0.2 mV/s时实现了216.8 mAh/g的特定容量.
- 展示了高容量保留 (90.7%在1000个循环后) 和基于NTP的阳极的新容量记录.
- 一个以海水为基础的ASIB电池表现出优越的能量和功率密度.
结论:
- 双涂层策略有效地提高了基于NTP的阳极的稳定性和性能.
- 这项工作为ASIBs开发长寿命,高性能阳极提供了可行的途径.
- 开发的阳极技术显示了实际大规模储能应用的潜力.
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