调节界面化学,使高功率双离子电池在低温度下使用成为可能
Jihui Lang1, Yuhan Liu1,2, Qirong Liu2
1Key Laboratory of Functional Materials Physics and Chemistry of the Ministry of Education, Jilin Normal University, Siping, 136000, China.
Small (Weinheim an der Bergstrasse, Germany)
|July 10, 2024
概括
研究人员开发了一种能级适应性电解质策略,以增强低温双离子电池 (DIB). 这种方法改善了接口化学,使得稳定的运行和在极寒条件下高速的性能成为先进的能量存储.
科学领域:
- 电化学 电化学 电化学
- 材料科学 材料科学 材料科学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 接口化学对于低温可充电电池的性能至关重要.
- 现有的接口工程面临着诸如电压下降和低温下不良高速放电等挑战.
研究的目的:
- 提出一种能级适应性电解质设计策略,用于调节低温酸石墨双离子电池 (DIB) 的接口化学.
- 为提高电池性能,构建具有卓越的离子转移动力学的强大的接口.
主要方法:
- 开发了一个能级适应电解质设计策略.
- 在石墨阴极上设计了溶剂/离子合的界面化学.
- 在金属阳极上促进了离子衍生界面化学.
主要成果:
- 在阴极上创建了含有N/P/S/F的有机丰富的间相,促进了离子转移和稳定性.
- 在阳极上形成了一个无机主导的富含LiF的介相,抑制树突,改善Li/剥离.
- 实现了广泛的操作温度范围 (-40至45°C).
- 在低温下表现出卓越的性能:在-40°C (1°C) 保持97.4%的容量,在10°C保持62.3%.
结论:
- 拟议的策略使得具有优越的离子动力学的强大的相间构造成为可能.
- 设计的DIB在广泛的温度范围内表现出卓越的电化学性能.
- 这项工作为开发高功率,低温可充电电池提供了可行的方法.
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