合成,表征和p-托利硫-功能化诺尔博纳/四旋旋风对的相互转换
Daniel Krappmann1, Andreas Hirsch1
1Department Chemistry and Pharmacy, Friedrich-Alexander-Universität Erlangen-Nürnberg, Nikolaus-Fiebiger Straße 10, 91058, Erlangen, Germany.
研究人员使用一组Para-tolylsulfone合成了新的norbornadiene/四旋旋气分子. 这些化合物表现出可调节的光物理性质,显示出未来应用的潜力.
科学领域:
- 有机化学 有机化学
- 摄影化学的使用.
- 材料科学 材料科学 材料科学
背景情况:
- 诺尔博纳/四旋旋风系统对于储能和分子开关具有价值.
- 电子吸收组对于调整它们的光物理性质至关重要.
研究的目的:
- 为了合成和描述新的2,3-非替代的norbornadiene/quadricyclane对.
- 为了研究-托利硫部分作为电子吸收组的作用.
- 为了比较托西尔替代系统的特性与先前研究的功能.
主要方法:
- 新的norbornadiene/quadricyclane衍生物的合成.
- 使用紫外线/Vis光谱和核磁共振 (NMR) 光谱进行综合性表征.
- 光物理性质分析,包括 λmax 和 λonset 的确定.
主要成果:
- 成功合成了一组2,3-非替代的norbornadiene/quadricyclane配对库,其中包含了para-tolylsulfone组.
- 托西尔部分表现出与功能的相似的光物理特性.
- 在乙二中实现了增强的红移,λmax高达394nm,λonset为469nm.
结论:
- -托利硫部分是norbornadiene/quadricyclane系统的一种可行的取代电子的取代剂.
- 开发的化合物具有适合潜在应用的光学特性.
- 进一步调查溶剂对异构化行为的影响是有必要的.
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