用不含的以太溶剂稀释电解质,用于4.5V金属电池
Yusi Yang1, Xiaofang Wang2, Jiacheng Zhu3
1School of Chemistry, Beihang University, Beijing, 100191, P.R. China.
Angewandte Chemie (International ed. in English)
|July 10, 2024
概括
这项研究引入了一种新的盐工程方法,用于高压金属电池 (LMB),使得使用无的以太电解质成为可能. 这种可持续的方法提高了电池性能,降低了成本和环境影响.
科学领域:
- 电化学 电化学 电化学
- 材料科学 材料科学 材料科学
- 可持续能源 可持续能源
背景情况:
- 高压金属电池 (LMB) 中的以太溶剂具有有限的氧化稳定性.
- 目前的解决方案涉及昂贵且对环境有害的化盐或溶剂.
研究的目的:
- 开发一种可持续且具有成本效益的电解质,用于使用无乙烯的高压LMB.
- 为了实现稳定的板剥离,并提高阴极性能.
主要方法:
- 提出了一种盐工程方法,使用稀释的,无的电解质.
- 研究了涂料剥离稳定性和阴极行为 (LiNi0.8Co0.1Mn0.1O2).
- 采用多模式实验表征和理论研究.
主要成果:
- 实现了稳定的涂层剥离,具有99.47%的库伦比克效率.
- 在NCM811阴极中缓解金属溶解,相位过渡和气体释放.
- 经过300个循环后,在4.5V Liidiye NCM811电池中证明了75.2%的容量保留.
结论:
- 含的盐是形成阳极和阴极上保护性被动化层的关键.
- 拟议的战略为在高压LMB中使用环保,低成本的以太提供了可行的替代方案.
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