相关实验视频
Updated: Jun 21, 2025

06:58
Zinc-Sponge Battery Electrodes that Suppress Dendrites
Published on: September 29, 2020
4.3K
离子度由外部海尔姆霍尔茨层中的离子体动态调节,以获得稳定的 Zn 阳极
Binyang Luo1, Hao Wang1, Chao Chen1
1Nanotechnology Research Institute/G60 STI Valley Industry & Innovation Institute/Key Laboratory of Yarn Materials Forming and Composite Processing Technology, College of Materials and Textile Engineering, Jiaxing University, Jiaxing 314000, China.
Journal of colloid and interface science
|July 11, 2024
概括
化 (HCQ) 添加到电解质中抑制了水性离子电池中的树的生长. 这促进了统一的化,显著延长了大规模储能电池的电池周期寿命.
科学领域:
- 电化学 电化学 电化学
- 材料科学 材料科学 材料科学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 树突的形成阻碍了水性离子电池的实际应用.
- 开发稳定高效的电解质对于大规模的储能解决方案至关重要.
研究的目的:
- 研究氧化 (HCQ) 作为一种电解质添加剂,以抑制树的生长.
- 了解HCQ促进均的机制.
主要方法:
- 扫描电子显微镜 (SEM) 观察涂层形态.
- 射线衍射光谱 (XRD) 用于分析晶体平面的生长.
- 现场微分电化学质谱 (DEMS) 检测气体演变.
- 在现场的光学显微镜可视化离子度动态.
主要成果:
- 添加HCQ导致平面涂,由SEM证实.
- XRD揭示了Zn (002) 平面的偏好增长,增强了稳定性.
- DEMS显示了减少的进化,表明对进化反应的抗性.
- 在现场显微镜表明HCQ的离子度的动态调节,促进甚至.
结论:
- 酸通过调节离子度在接口上有效抑制树突.
- 修改后的电解质显著提高了离子电池的循环寿命和库伦比效率.
- 该战略推动了用于储能的实际水性离子电池的开发.
相关概念视频
Standard Electrode Potentials
43.7K
On comparing the reactivity of silver and lead, it is observed that the two ionic species, Ag+ (aq) and Pb2+ (aq), show a difference in their redox reactivity towards copper: the silver ion undergoes spontaneous reduction, while the lead ion does not. This relative redox activity can be easily quantified in electrochemical cells by a property called cell potential. This property is commonly known as cell voltage in electrochemistry, and it is a measure of the energy which accompanies the charge...
43.7K
Concentration Cells
22.5K
A concentration cell is a type of a voltaic cell constructed by connecting two almost identical half-cells, both based on the same half-reaction and using the same electrode, differing only in the concentration of one redox species. A concentration cell's potential, therefore, is determined only by the concentration difference of the particular redox species.
Consider the following voltaic cell:
Consider the following voltaic cell:
22.5K
Formation of Complex Ions
23.6K
A type of Lewis acid-base chemistry involves the formation of a complex ion (or a coordination complex) comprising a central atom, typically a transition metal cation, surrounded by ions or molecules called ligands. These ligands can be neutral molecules like H2O or NH3, or ions such as CN− or OH−. Often, the ligands act as Lewis bases, donating a pair of electrons to the central atom. These types of Lewis acid-base reactions are examples of a broad subdiscipline called coordination...
23.6K
EDTA: Auxiliary Complexing Reagents
575
EDTA titrations are usually carried out in highly basic conditions, where the fully deprotonated form of EDTA, Y4−, actively complexes with the free metal ions in the solution. Several metal ions precipitate as hydrous oxide (hydroxides, oxides, or oxyhydroxides) under these conditions, lowering the concentration of free metal ions in the solution. For this reason, auxiliary complexing agents or ligands such as ammonia, tartrate, citrate, or triethanolamine are used in EDTA titrations to...
575
Extraction: Advanced Methods
444
Metal ions can be separated from one another by complexation with organic ligands–the chelating agent– to form uncharged chelates. Here, the chelating agent must contain hydrophobic groups and behave as a weak acid, losing a proton to bind with the metal. Since most organic ligands used in this process are insoluble or undergo oxidation in the aqueous phase, the chelating agent is initially added to the organic phase and extracted into the aqueous phase. The metal-ligand complex is...
444
Electrodeposition
625
Electrodeposition is a technique used to separate an analyte from interferents by electrochemical processes. Here, the analyte is a metal ion that can be deposited on an electrode immersed in the sample solution. The electrochemical setup consists of an anode and a cathode. When an electric current is applied to the setup, oxidation occurs at the anode. At the cathode, which consists of a large metal surface, metal ions undergo reduction and deposit onto the surface.
Electrodeposition can...
Electrodeposition can...
625

