质子集体量子道引发了冰在压力下异常的导热性
Yufeng Wang1,2, Ripeng Luo2, Jian Chen3
1Tsinghua Shenzhen International Graduate School, <a href="https://ror.org/03cve4549">Tsinghua University</a>, Shenzhen 518055, China.
冰中的质子道在高压下表现出集体行为,影响热导率. 这种量子运动跨越纳米和皮秒,影响声子散射,揭示了全球量子效应.
科学领域:
- 凝聚物质物理学 凝聚物质物理学
- 量子力学就是量子力学.
- 材料科学是一种材料科学.
背景情况:
- 冰中的质子道通常被认为是非局部的,但范围有限.
- 了解极端条件下的材料中的量子效应至关重要.
研究的目的:
- 为了研究高压下的冰中质子道的行为.
- 探索压力,热导率和冰中的量子现象之间的关系.
主要方法:
- 试验测量冰的热导率高达50 GPa.
- 大规模的量子分子动力学模拟.
主要成果:
- 导热率增加到20 GPa,然后在更高的压力下降.
- 非单调的导热性归因于高压下集体质子道化.
- 模拟显示了跨越纳米和皮秒的集体道循环.
结论:
- 在高压冰中直接证明了全球量子运动.
- 集体质子道化显著影响声子散射和热传输.
- 提供了对声子传播和原子道的合的新见解.
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