研究超吸收性聚合物尺寸对吸收和水泥糊病理学的影响
Nilam Adsul1, Jun-Woo Lee1, Su-Tae Kang2
1Department of Civil Engineering, Daegu University, Gyeongsan 38453, Republic of Korea.
Materials (Basel, Switzerland)
|July 13, 2024
概括
超吸收性聚合物 (SAP) 在性条件下表现出不同的吸水能力,影响水泥糊的质学. 较小的SAP吸收更多,但在高度性水泥过物中性能降低.
科学领域:
- 材料科学与工程 材料科学与工程
- 建筑材料 建筑材料
- 聚合物科学 聚合物科学
背景情况:
- 使用超吸收聚合物 (SAP) 的内部固化是一种有前途的技术,可以改善混凝土的性能.
- 了解SAP在性环境中的行为,如水泥孔隙溶液,对于它们的有效应用至关重要.
- SAP 尺寸和度对水的吸收和水泥糊的整形学的影响需要详细的研究.
研究的目的:
- 评估两种基于聚烯的SAPs (28微米和80微米) 在性溶液 (pH7,11,13,水泥液) 中的吸水能力.
- 评估SAP对水泥的气质特性 (塑料粘度,产量应力) 的影响,在不同的水-水泥比率和SAP剂量下.
- 为了比较水泥配方中干燥与湿 (预浸泡) SAP 的性能.
主要方法:
- 在不同pH的溶液中,对两种SAP大小进行了吸收能力测试.
- 用不同的SAP剂量和水与水泥比率修改的水泥糊的风湿性质被测量.
- 干燥和湿SAP之间进行了比较,以及SAP修改和参考水泥糊之间进行了比较.
主要成果:
- 在所有测试的pH水平上,较小的SAP (28微米) 显示出比较大的SAP (80微米) 更高的吸水率.
- 这两种SAP类型都在高度性水泥过物 (pH 13.73) 中表现出降低的吸收和早期脱落.
- 添加SAP通常会增加水泥粘度和产量压力,特别是在较低的w/c比率 (0.4,0.5) 和较高的SAP剂量下,这表明持续的吸水. 潮湿的SAP产生了比干燥的SAP更高的气动学值.
结论:
- SAPs的保留水量受到环境度的显著影响,在高度性条件下性能下降.
- SAP,特别是较小的SAP,可以增强水泥糊的整形学,但它们的有效性取决于SAP条件 (干/湿) 和混合设计.
- 需要进一步的研究来优化SAP用于内部固化,考虑到性水泥环境带来的挑战.
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