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相关概念视频

Ion Exchange01:17

Ion Exchange

573
Ion exchange chromatography separates charged molecules from a solution by reversibly exchanging them with mobile, or 'active', ions associated with the oppositely charged stationary phase. This method can be used to separate ions, soften and deionize water, and purify solutions. The polymers comprising the ion-exchange column are high-molecular-weight and chemically stable polymers, crosslinked to be porous and essentially insoluble. They are also functionalized with either acidic or...
573
Potentiometry: Membrane Electrodes01:15

Potentiometry: Membrane Electrodes

547
Membrane electrodes, also known as p-ion electrodes, use membranes that selectively interact with free analyte ions, generating a potential difference across the membrane. The resulting membrane potential, known as the asymmetry potential, is not zero even when analyte concentrations on both sides of the membrane are equal. The membrane's response is typically not selective to a single analyte but proportional to the concentration of all ions in the sample solution capable of interacting at...
547
Ion-Exchange Chromatography01:09

Ion-Exchange Chromatography

442
Ion-exchange chromatography, or IEC, is a technique for separating ions based on their affinity for the stationary phase. The stationary phase is a cross-linked polymer resin with covalently attached ionic functional groups. The functional groups can be either positively charged (cation exchangers) or negatively charged (anion exchangers). A cation exchanger consists of a polymeric anion and active cations, while an anion exchanger is a polymeric cation with active anions. The choice of...
442
Ionic Bonding and Electron Transfer02:48

Ionic Bonding and Electron Transfer

41.4K
Ions are atoms or molecules bearing an electrical charge. A cation (a positive ion) forms when a neutral atom loses one or more electrons from its valence shell, and an anion (a negative ion) forms when a neutral atom gains one or more electrons in its valence shell. Compounds composed of ions are called ionic compounds (or salts), and their constituent ions are held together by ionic bonds: electrostatic forces of attraction between oppositely charged cations and anions. 
41.4K
Molecular and Ionic Solids02:54

Molecular and Ionic Solids

17.1K
Crystalline solids are divided into four types: molecular, ionic, metallic, and covalent network based on the type of constituent units and their interparticle interactions.
Molecular Solids
Molecular crystalline solids, such as ice, sucrose (table sugar), and iodine, are solids that are composed of neutral molecules as their constituent units. These molecules are held together by weak intermolecular forces such as London dispersion forces, dipole-dipole interactions, or hydrogen bonds, which...
17.1K
Batteries and Fuel Cells03:12

Batteries and Fuel Cells

27.3K
A battery is a galvanic cell that is used as a source of electrical power for specific applications. Modern batteries exist in a multitude of forms to accommodate various applications, from tiny button batteries such as those that power wristwatches to the very large batteries used to supply backup energy to municipal power grids. Some batteries are designed for single-use applications and cannot be recharged (primary cells), while others are based on conveniently reversible cell reactions that...
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相关实验视频

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Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications
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Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications

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聚合物固态离子电池的复合离子凝电极

Noah B Schorr1, Austin Bhandarkar2, Josefine D McBrayer1

  • 1Department of Power Sources R&D, Sandia National Laboratories, Albuquerque, NM 87123, USA.

Polymers
|July 13, 2024
PubMed
概括

研究人员开发了来自离子凝的固态电解质,用于高性能离子电池. 这种可扩展的方法可以在复合电极中实现高活性材料负载,以提高能量密度和稳定的循环.

科学领域:

  • 材料科学 材料科学 材料科学
  • 电化学 电化学 电化学
  • 储能 储能 储能 储能 储能 储能

背景情况:

  • 在可充电电池中实现高能量和功率密度对于电动汽车和便携式电子设备等应用至关重要.
  • 固态电池比传统的离子电池具有潜在的安全优势,但电极设计仍然是一个重大挑战.
  • 电极中的高活性物质负载对于实际的能量密度至关重要,但在固态系统中难以实现.

研究的目的:

  • 为固态离子电池制造具有高活性物质负载的复合电极开发一种新的战略.
  • 研究来自离子凝的固态电解质在实现可扩展制造高性能电池方面的性能.
  • 展示这些复合电极和电解质在实现高容量利用和稳定的循环中的潜力.

主要方法:

  • 利用来自离子凝的固态电解质 (SSEs) 来制造复合电极.
  • 在复合酸电极中的调前体和活性物质组成.
  • 制造和测试的全聚合物固态电池,包括复合阳极和铁酸盐阴极与离子凝SSEs.

主要成果:

  • 使用可扩展的方法实现了高活性物质负载 (>10 mg/cm2,~9 mA/cm2在1C).
  • 在复合酸电极中,在C/5速率下显示了近乎理论的容量利用率.
关键词:
离子电池是一种离子电池.离子凝 (Ionogel) 是一种聚合物电解质的高分子电解质.固态电解质 固态电解质

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Characterization of Electrode Materials for Lithium Ion and Sodium Ion Batteries Using Synchrotron Radiation Techniques
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Synthesis of Ionic Liquid Based Electrolytes, Assembly of Li-ion Batteries, and Measurements of Performance at High Temperature
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Synthesis of Ionic Liquid Based Electrolytes, Assembly of Li-ion Batteries, and Measurements of Performance at High Temperature

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Synthesis of Ionic Liquid Based Electrolytes, Assembly of Li-ion Batteries, and Measurements of Performance at High Temperature
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  • 在室温下达到5.85mA/cm2 (11.70A/g) 的稳定循环,平均库伦比效率超过99%.
  • 展示了一个完整的固态电池,在1C速率下稳定循环.
  • 结论:

    • 来自离子凝的SSE为高性能固态离子电池的可扩展制造提供了可行的途径.
    • 开发的复合电极策略有效地解决了高活性材料负载的挑战.
    • 这些进步为更安全,更高能量密度的固态电池铺平了道路.