工程可逆交联弹性体向灵活和可回收的弹性体/碳纤维复合材料,具有非凡的抗撕裂性
1State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun, 130012, P. R. China.
Advanced materials (Deerfield Beach, Fla.)
|July 15, 2024
概括
新的灵活,可回收的碳纤维复合材料为防护装备提供了增强的抗撕裂性能. 这些先进的材料使用了新的聚氨结合剂,以获得更高的强度和可回收性.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物化学 聚合物化学
- 复合材料 复合材料 复合材料
背景情况:
- 碳纤维 (CF) 增强聚合物 (CFRPs) 在个人防护设备方面表现有前途.
- 现有的CFRP是刚性的,不可回收利用的,并且缺乏抗撕裂的性能.
研究的目的:
- 开发灵活,可回收和耐撕裂的聚氨 (PU) -CF复合材料.
- 调查增强机械性能和可回收性背后的机制.
主要方法:
- 使用可逆交联PU弹性体粘合剂和CF织物制造PU-CF复合材料.
- 机械性能的表征,包括强度和断裂能量.
- 分析PU结合剂内的超分子相互作用和与CF的界面粘附.
主要成果:
- 实现了高强度 (767 MPa) 和创纪录的断裂能量 (2012 kJ m-2).
- 由于PU结合剂的有效力分布,证明了增强的抗撕裂性.
- 通过动态PU结合剂的解离,确认了PU-CF复合材料的可回收性.
结论:
- 开发的PU-CF复合材料提供了灵活性,可回收利用性,强度和抗撕裂性能的卓越组合.
- 聚氨酸结合剂中的层次超分子相互作用是高性能的关键.
- 这些复合材料代表了个人防护设备及其他领域应用的重大进步.
相关概念视频
Fiber Reinforced Concrete
73
Fiber-reinforced concrete significantly enhances the structural and nonstructural properties of traditional concrete by incorporating fibers like steel, glass, and polymers. These fibers, varying from natural ones such as sisal and cellulose to manufactured ones like polypropylene and Kevlar, are mixed into hydraulic cement with aggregates. Steel fibers, often preferred for their robustness, contribute to improved ductility, toughness, and post-cracking performance. The concrete is classified...
73
Types of Step-Growth Polymers: Polyesters
2.2K
The introduction of polyesters has brought major development to the textile industry. The wrinkle-free behavior of polyester blends has eliminated the need for starching and ironing clothes.
Polyesters are commonly prepared from terephthalic acid and ethylene glycol; the crude product is known as poly(ethylene terephthalate) or PET. However, polyesters are synthesized industrially by transesterification of dimethyl terephthalate with ethylene glycol at 150 °C. The two reactants and the...
Polyesters are commonly prepared from terephthalic acid and ethylene glycol; the crude product is known as poly(ethylene terephthalate) or PET. However, polyesters are synthesized industrially by transesterification of dimethyl terephthalate with ethylene glycol at 150 °C. The two reactants and the...
2.2K
Members Made of Elastoplastic Material
94
The behavior of elastoplastic materials under bending stresses, particularly in structural members with rectangular cross-sections, is crucial for predicting material responses and understanding failure modes. Initially, when a bending moment is applied, the stress distribution across the section follows Hooke's Law and is linear and elastic. This distribution means the stress increases from the neutral axis to the maximum at the outer fibers, up to the elastic limit.
As the bending moment...
As the bending moment...
94
Polymer Classification: Architecture
2.7K
Polymers are classified as linear or branched on the basis of their chain architecture. The polymer chains in linear polymers have a long chain-like structure with minimal to no branching at all. Even if a polymer features large substituent groups on the monomer, which appear as branches to the skeleton, it is not considered a branched polymer. A branched polymer contains secondary polymer chains that arise from the main polymer chain. The branching occurs when the polymer growth shifts from...
2.7K
Reinforcements in Concrete
82
Reinforced concrete is a composite material used extensively in construction, combining the compressive strength of concrete with the tensile strength of steel. This synergy is essential as concrete, while excellent at resisting compression, is weak under tension. Steel bars, or rebars, are embedded in the concrete to handle these tensile forces. The choice of steel is strategic; it shares a similar coefficient of thermal expansion with concrete, which ensures uniformity in response to...
82


