来自含铁的泥的铁基催化剂,用于提高H2S选择性催化氧化的催化性能
Runtian He1, Xiaoyu Zhang1, Jia-Nan Gu1
1School of Environmental Science and Engineering, Shanghai Jiao Tong University, 800 Dongchuan Road, Shanghai 200240, P.R. China.
来自污泥的铁基催化剂有效氧化硫化 (H2S). 通过在500°C时化并用2M NaOH处理的催化剂获得最佳性能,显示出增强的表面性能.
科学领域:
- 材料科学 材料科学 材料科学
- 催化剂是一种催化剂.
- 环境化学环境化学
背景情况:
- 硫化 (H2S) 是一种有毒和腐蚀性气体,需要有效地从工业来源中去除.
- 含铁的污泥是开发新型催化材料的未充分利用的资源.
研究的目的:
- 从污泥中制备和优化用于H2S选择性催化氧化的铁基催化剂.
- 研究烧温度和性处理对催化剂性能的影响.
主要方法:
- 在不同温度下对含铁的污泥进行化.
- 使用不同度的NaOH溶液对催化剂进行性处理.
- 使用N2-Brunauer-Emmett-Teller (N2-BET),X射线光电子谱学 (XPS),O2-温度编程溶解 (O2-TPD) 和CO2-TPD进行表征.
主要成果:
- 在500°C (S-500) 烧焦的催化剂表现出极好的H2S氧化活性.
- 通过2M NaOH (S-500(2.0) 的性处理进一步优化,产生了最高的催化活性.
- S-500(2.0) 催化剂显示了更小的粒子大小,更大的外表面积,更高的Fe3+和表面吸附氧含量,增加的氧空缺,以及更弱的性位点.
结论:
- 泥产生的铁基催化剂对于H2S选择性氧化是有效的.
- 优化化和性处理显著提高了催化性能.
- S-500 ((2.0) 催化剂的优越活性归因于其有利的物理化学特性,包括表面积,活性点和氧气空缺.
更多相关视频
08:40Synthesis of Metal Nanoparticles Supported on Carbon Nanotube with Doped Co and N Atoms and its Catalytic Applications in Hydrogen Production
Published on: December 6, 2021
15:19Development of Sulfidogenic Sludge from Marine Sediments and Trichloroethylene Reduction in an Upflow Anaerobic Sludge Blanket Reactor
Published on: October 15, 2015
相关概念视频
Catalysis
Reduction of Alkenes: Asymmetric Catalytic Hydrogenation
The metal catalyst used can be either heterogeneous or homogeneous. When hydrogenation of an alkene generates a chiral center, a pair of enantiomeric products is expected to form. However, an enantiomeric excess of one of the products can be facilitated using an enantioselective reaction or an...
Reduction of Alkenes: Catalytic Hydrogenation
Metals like palladium, platinum, and nickel are commonly used in their solid forms — fine powder on an inert surface. As these catalysts remain insoluble in the reaction mixture, they are referred to as heterogeneous catalysts.
The hydrogenation process takes place on the...
Oxidation of Alkenes: Syn Dihydroxylation with Osmium Tetraoxide
