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Updated: Jun 21, 2025

Accessing Valuable Ligand Supports for Transition Metals: A Modified, Intermediate Scale Preparation of 1,2,3,4,5-Pentamethylcyclopentadiene
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Accessing Valuable Ligand Supports for Transition Metals: A Modified, Intermediate Scale Preparation of 1,2,3,4,5-Pentamethylcyclopentadiene

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关于醇+H2的H原子抽象反应的理论研究,第一部分:五个分支醇异构体

Jin-Tao Chen1,2, Yueying Liang3, Haoyuan Lang1

  • 1School of Energy and Power Engineering, Beihang University, Beijing 100191, P. R. China. chongwen.zhou@universityofgalway.ie.

Physical chemistry chemical physics : PCCP
|July 15, 2024
PubMed
概括

本研究详细介绍了使用先进的计算方法与分支醇的氧基反应的化学动力学. 这些发现为建模这些化合物的氧化提供了关键数据.

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An alkene, such as propene, reacts with bromine in the presence of water to yield a halohydrin. Halohydrins contain a halogen and a hydroxyl group attached to adjacent carbons. When the halogen is bromine, it is called a bromohydrin, while a chlorohydrin has chlorine as the halogen.
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Organic compounds of the same molecular formula can have different structural formulas called constitutional isomers, and the phenomenon is known as constitutional isomerism. Alkanes with four or more carbons showing multiple structures with the same molecular formula thereby exhibit constitutional isomerism.
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The rate of acid-catalyzed hydration of alkenes depends on the alkene's structure, as the presence of alkyl substituents at the double bond can significantly influence the rate.
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