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Updated: Jun 21, 2025

Efficient Construction of Drug-like Bispirocyclic Scaffolds Via Organocatalytic Cycloadditions of α-Imino γ-Lactones and Alkylidene Pyrazolones
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Efficient Construction of Drug-like Bispirocyclic Scaffolds Via Organocatalytic Cycloadditions of α-Imino γ-Lactones and Alkylidene Pyrazolones

Published on: February 7, 2019

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不对称的动态分辨率 通过轴切尔尿/二元器官催化剂介导的 Racemic Lactide 的聚合

Guojie Li1, Peng Du1, Guangqiang Xu1,2,3

  • 1Key Laboratory of Photoelectric Conversion and Utilization of Solar Energy, Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao, 266101, China.

Chemistry (Weinheim an der Bergstrasse, Germany)
|July 15, 2024
PubMed
概括

这项研究引入了用于rac-LA (rac-LA) 的非对称动力分辨率聚合 (AKRP) 的新型性二元器官催化剂. 这些催化剂在室温下达到高活性和选择性,产生高性能立体积聚酸 (PLA).

关键词:
非对称的动力分辨率聚合物化.轴性 - 性尿酸.二元器官催化系统是二元器官催化系统.酸基酸基的基础拉塞米亚的乳化物.

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Racemic Mixtures and the Resolution of Enantiomers

A racemic mixture, or racemate, is an equimolar mixture of enantiomers of a molecule that can be separated using their unique interaction with chiral molecules or media. Racemic mixtures are denoted by the (±)- prefix. This ‘optical rotation descriptor’ applies to the whole solution of a racemic mixture rather than a specific stereoisomer. Enantiomers typically have the same physical and chemical properties. Hence, they are not easily separable. However, enantiomers can exhibit...
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Halogenation to form a new chiral center:
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