在磁场中的微滴中,层次纳米粒子架构的空间封闭组装和固定
Abhirup Basu1, Matthew R Clary2, Joseph B Tracy2
1Department of Chemical & Biomolecular Engineering, North Carolina State University, Raleigh, North Carolina 27695, United States.
ACS nano
|July 15, 2024
概括
将磁纳米粒子限制在微球中,将它们的组装引导到不同的结构中. 这些磁性微珠为光学调制器和微滚筒等应用提供可调节的响应.
科学领域:
- 体科学是一种体科学.
- 材料科学是一种材料科学.
- 纳米技术 纳米技术
背景情况:
- 磁场导向的合体组件在散装媒体上得到了很好的研究.
- 在封闭的微环境中组装行为仍然不太了解.
研究的目的:
- 研究纳米粒子在狭窄的微球中的磁性组合.
- 探索层次性的磁性架构的结构-属性关系.
主要方法:
- 在聚二甲基 (PDMS) 微滴中分散氧化铁磁纳米粒子 (MNPs).
- 应用静态磁场来指导MNP组件.
- 通过COMSOL模拟分析微结构.
- 治疗PDMS以形成稳定的微珠.
主要成果:
- 多种NP度决定了组装:线性链 (低),链/捆绑 (中等),3D捆绑 (高).
- 能量的最小化驱动链的横向聚合到带有注册表外双极的捆绑中.
- 固化的微珠表现出可调节的磁性宏观响应.
结论:
- 微球中的限制使得控制的层次性磁性组合成为可能.
- 软磁性微珠为可调节的磁相互作用提供了一个多功能平台.
- 这些微珠显示出在光学调制器和微卷轴器中的应用潜力.
更多相关视频
10:17Patterning of Microorganisms and Microparticles through Sequential Capillarity-assisted Assembly
Published on: November 4, 2021
3.2K
09:58Computer Numerical Control Micromilling of a Microfluidic Acrylic Device with a Staggered Restriction for Magnetic Nanoparticle-Based Immunoassays
Published on: June 23, 2022
2.1K
相关概念视频
Metallic Solids
Metallic solids such as crystals of copper, aluminum, and iron are formed by metal atoms. The structure of metallic crystals is often described as a uniform distribution of atomic nuclei within a “sea” of delocalized electrons. The atoms within such a metallic solid are held together by a unique force known as metallic bonding that gives rise to many useful and varied bulk properties.
All metallic solids exhibit high thermal and electrical conductivity, metallic luster, and malleability. Many...
All metallic solids exhibit high thermal and electrical conductivity, metallic luster, and malleability. Many...
Atomic Nuclei: Nuclear Relaxation Processes
In the absence of an external magnetic field, nuclear spin states are degenerate and randomly oriented. When a magnetic field is applied, the spins begin to precess and orient themselves along (lower energy) or against (higher energy) the direction of the field. At equilibrium, a slight excess population of spins exists in the lower energy state. Because the direction of the magnetic field is fixed as the z-axis, the precessing magnetic moments are randomly oriented around the z-axis. This...
Diamagnetic Shielding of Nuclei: Local Diamagnetic Current
An applied magnetic field causes the electrons present in the molecule to circulate, setting up a local diamagnetic current within the molecule. The local diamagnetic current arising from circulating sigma-bonding electrons induces a magnetic field, Blocal that opposes the applied magnetic field, B0. The effective magnetic field experienced by these nuclei is given by the difference between the applied and local magnetic fields in a phenomenon called local diamagnetic shielding. Essentially,...
Magnetic Fields
A moving charge or a current creates a magnetic field in the surrounding space, in addition to its electric field. The magnetic field exerts a force on any other moving charge or current that is present in the field. Like an electric field, the magnetic field is also a vector field. At any position, the direction of the magnetic field is defined as the direction in which the north pole of a compass needle points.
A magnetic field is defined by the force that a charged particle experiences...
A magnetic field is defined by the force that a charged particle experiences...
Magnetic Flux
The magnetic flux measures the number of magnetic field lines passing through a given surface area. The SI unit for magnetic flux is the weber (Wb). Magnetic flux is a scalar quantity. It depends on three factors: the strength of the magnetic field B, the area through which the field lines pass, and the relative orientation of the field with the surface area.
Suppose a surface is divided into elements of area dA. For each element, the component of the magnetic field that is normal to the...
Suppose a surface is divided into elements of area dA. For each element, the component of the magnetic field that is normal to the...
Ferromagnetism
Materials like iron, nickel, and cobalt consist of magnetic domains, within which the magnetic dipoles are arranged parallel to each other. The magnetic dipoles are rigidly aligned in the same direction within a domain by quantum mechanical coupling among the atoms. This coupling is so strong that even thermal agitation at room temperature cannot break it. The result is that each domain has a net dipole moment. However, some materials have weaker coupling, and are ferromagnetic at lower...
