在0.1固溶液合金中,Mg0.9的温度依赖的化行为和储能热力学
Yingyu Xu1, Cong Peng1, Qingan Zhang1
1School of Materials Science and Engineering, Anhui University of Technology, Maanshan 243002, China. qazhang@ahut.edu.cn.
Dalton transactions (Cambridge, England : 2003)
|July 16, 2024
概括
这项研究阐明了- (Mg-In) 合金中的储存机制. 这项研究揭示了Mg(In) 固体溶液如何经历化和脱,为可逆反应提供了洞察力.
科学领域:
- 材料科学 材料科学 材料科学
- 固态化学 固态化学
- 储存技术 储存技术
背景情况:
- 基于的合金对的储存有希望.
- 了解等合金元素的作用对于优化性能至关重要.
- 固体溶液中的储机制需要详细的研究.
研究的目的:
- 为了阐明Mg(In) 固体溶液的储存机制.
- 系统地研究Mg0.9In0.1合金的化和脱特性.
- 为Mg-In系统中的可逆储反应提供新的见解.
主要方法:
- 化和脱的系统研究.
- 在气氛下对合金特性进行分析.
- 对反应热力学多态效应的研究.
主要成果:
- Mg0.9In0.1 合金化物到 Mg3In 和 MgH2.
- Mg3In的多态性影响化特征和脱化度.
- 在340°C以上,可逆化到 (Mg1-xInx) 3In和MgH2发生.
- 无论是β'-Mg3In还是β-Mg3In,都表现出具有斜坡高原的可逆反应.
结论:
- 这项研究阐明了Mg(In) 固体溶液中复杂的储存机制.
- Mg3In的多态性在储存的热力学中起着重要作用.
- (Mg) 合金显示出可逆存储应用的潜力.
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