三种吸附剂的比较,用于从水中微微提取薄膜固体阶段的酸
Petra van der Merwe1, Patricia Forbes1
1Department of Chemistry, Faculty of Natural and Agricultural Sciences, University of Pretoria, South Africa. patricia.forbes@up.ac.za.
Analytical methods : advancing methods and applications
|July 16, 2024
概括
一种新的薄膜提取方法有效量化水中的酸 (HAAs). 这种技术提供了一种坚固,快速和负担得起的方法来测量这些潜在致癌的消毒副产品.
科学领域:
- 环境化学环境化学
- 分析化学 分析化学
背景情况:
- 消毒副产品 (DBPs),如酸 (HAAs),在水处理过程中形成,并带来健康风险,包括致癌性.
- 越来越多的监管审查需要稳健,快速和具有成本效益的分析方法来量化DBP.
研究的目的:
- 开发和评估薄膜提取方法,以有效分析水中的酸.
- 为了比较不同薄膜组合的提取性能.
主要方法:
- 内部合成使用旋转涂层的薄膜,允许可调节的吸附剂选择和薄膜几何.
- 测试PDMS,Carboxen®和HLB吸附剂的提取潜力,在各种薄膜配置中测试加水中的HAA.
- 使用计算模型分析和比较PDMS和HLB提取机制.
主要成果:
- 与普通PDMS薄膜相比,用HLB或Carboxen®浸的PDMS薄膜显著增强了HAA提取.
- 经过HLB浸的薄膜显示了三替代HAA的高提取效率 (例如,TBAA的92%).
- 计算建模结果与实验数据相关联,表明通过键的物理吸收作为主要提取机制.
结论:
- 薄膜提取,特别是用HLB浸的薄膜,为HAA提供了有效的分析方法.
- 开发的方法适用于量化HAA,包括非常低度的HAA.
- 这项研究验证了计算建模在预测提取性能方面的使用.
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