在周期性半孔有机 (PMOs) 中被封闭的冰的结构
Niels C Gießelmann1, Philip Lenz2,3, Sophia-Marie Meinert2
1Deutsches Elektronen-Synchrotron DESY, Notkestr. 85, 22607 Hamburg, Germany.
The Journal of chemical physics
|July 17, 2024
概括
冰的结构在纳米孔隙材料内发生变化,揭示了六角形和立方体冰 I. 格子参数根据孔径大小和表面化学变化,影响冰晶的方向.
科学领域:
- 材料科学 材料科学 材料科学
- 凝聚物质物理学 凝聚物质物理学
- 纳米技术 纳米技术
背景情况:
- 对于各种科学领域来说,了解被封闭的冰形成是至关重要的.
- 纳米孔状材料提供了独特的环境来研究相位过渡.
- 周期性半孔有机 (PMOs) 提供可调节的孔径和表面化学成分.
研究的目的:
- 为了研究被限制在PMOs内的冰的结构转变.
- 为了确定孔径和表面功能对冰结构的影响.
- 为了分析封闭的冰晶的方向.
主要方法:
- 在PMO上进行了X射线散射测量,孔径从3.4到4.9纳米不等.
- 实验是在290K和150K之间的温度下进行的.
- 使用X射线交叉相关性分析来研究冰晶的方向.
主要成果:
- 在纳米多孔中观察到具有六角形和立方形特征的冰I.
- 封闭式冰的格子参数与散装冰不同,并根据孔径大小和表面化学变化而变化.
- 检测到六角冰晶相对于孔壁的偏好方向.
- 具有~3.8纳米直径的水友性功能化的毛孔显示出更强的相关性和晶格参数转移.
结论:
- 纳米孔隙封闭显著改变冰结构,导致混合六角和立方相.
- 孔径和表面化学是控制封闭冰结构和格子参数的关键因素.
- 表面相互作用影响纳米孔内的冰的方向和结构演变.
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