核心外纳米凝:形态,电静电和磁静电相互作用的影响
Alla B Dobroserdova1, Elena S Minina2, Pedro A Sánchez2
1Ural Federal University, Ekaterinburg, Russian Federation. alla.dobroserdova@urfu.ru.
纳米凝结构受到核心外形态和单体相互作用的影响. 充电的纳米凝表现出增强的聚合物背折叠,而磁性纳米颗粒影响磁性易感性,特别是具有功能化的外.
科学领域:
- 聚合物科学 聚合物科学
- 材料科学 材料科学 材料科学
- 计算化学计算化学
背景情况:
- 纳米凝是具有可调节性质的多功能聚合物纳米粒子.
- 核心外纳米提供独特的结构和功能可能性.
- 了解纳米凝形态对于设计先进材料至关重要.
研究的目的:
- 研究核心外形态对纳米凝结构特征的影响.
- 探索单体间相互作用的影响,包括电荷和磁性纳米粒子,纳米凝的形成.
- 确定纳米凝结构如何影响磁性.
主要方法:
- 利用先进的计算机模拟来建模纳米凝系统.
- 检查了三个不同的系统:仅排除体积,带电单体与排除体积,并排除体积与磁纳米粒子.
- 分析了聚合物链行为,包括核心透和外功能化.
主要成果:
- 观察到聚合物背折叠 (外穿透到核心) 在短,密集的外中,由充电的单体增强.
- 发现实验相关量的磁纳米粒子并没有显著改变纳米凝形态.
- 展示了纳米凝形态和磁性易感性之间的相关性,在功能化的长中增强了磁性反应.
结论:
- 核心外形态和单体间相互作用显著决定了纳米凝结构.
- 充电相互作用促进了纳米凝中的聚合物背折叠.
- 磁性纳米颗粒的结合影响了磁性特性,而不是总体形态,为磁性响应调整提供了途径.
更多相关视频
12:07Fabricating Degradable Thermoresponsive Hydrogels on Multiple Length Scales via Reactive Extrusion, Microfluidics, Self-assembly, and Electrospinning
Published on: April 16, 2018
09:12Functionalization of Single-walled Carbon Nanotubes with Thermo-reversible Block Copolymers and Characterization by Small-angle Neutron Scattering
Published on: June 1, 2016
相关概念视频
Noncovalent Attractions in Biomolecules
Four types of noncovalent interactions are hydrogen bonds, van der Waals forces, ionic bonds, and hydrophobic interactions.
Hydrogen bonding results from the electrostatic attraction of a hydrogen atom covalently bonded to a strong-electronegative atom like oxygen,...
Diamagnetic Shielding of Nuclei: Local Diamagnetic Current
Energetics of Solution Formation
When the strengths of the intermolecular forces of attraction between solute and solvent species in a solution are no different than those present in the separated components, the solution is formed with no accompanying energy change. Formation of the solution requires the solute–solute and solvent–solvent...
Colloidal precipitates
Molecular Shape and Polarity
Electric Field of a Non Uniformly Charged Sphere
Consider a non-uniformly charged sphere, for which the density of charge depends only on the distance from a point in space and not on the direction. Such a sphere has a spherically symmetrical charge distribution. Here, the electric...
