剪流对聚合物化的横向导热率的影响
1Graduate School of Information Science, <a href="https://ror.org/0151bmh98">University of Hyogo</a>, Kobe 650-0047, Japan.
Physical review. E
|July 18, 2024
概括
这项研究表明,应力热规则准确地描述了在剪切流下纠的聚合物融中的导热性. 这一发现支持其在聚合物融模拟中的使用.
科学领域:
- 聚合物物理 聚合物物理
- 类风病学 类风病学 类风病学
- 计算材料科学科学 计算材料科学
背景情况:
- 了解流动下聚合物化的热传输对于材料加工至关重要.
- 现有的方法很难准确地测量热导率,横向切割流.
- 应力热规则 (STR) 与应力和导热性有关,但其在切割条件下的有效性仍有争议.
研究的目的:
- 为了研究剪切流对聚合物化的导热率的影响.
- 扩展逆不平衡分子动力学 (RNEMD) 方法,用于同时生成温度和速度梯度.
- 为了验证聚合物在切削流下化的应力热规则 (STR).
主要方法:
- 使用了修改后的反向不平衡分子动力学 (RNEMD) 方法.
- 同时生成温度和流速的空间梯度.
- 测量的导热率横向与剪切流的方向.
主要成果:
- 森伯格数有效地区分了跨聚合物链长度的导热率的剪切速率依赖.
- 应力热规则 (STR) 适用于纠的聚合物化物,但不适用于在剪切下未纠的聚合物.
- 应力热系数在纠的融中独立于链条长度,在剪切下比静止状态更小.
结论:
- 证实了压力热规则 (STR) 对聚合物化的有效性,即使在剪切流下.
- STR可以作为聚合物化的热流体动力学模拟的组成方程.
- 这些发现对聚合物加工中的计算建模和工程应用具有广泛的意义.
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