新型除泡剂的合成和水泥制剂的表征
Francesco Taddeo1, Rosa Vitiello1, Michela Ruocco1
1University of Naples Federico II, Department of Chemical Sciences, Complesso Universitario di Monte Sant'Angelo, 80126, Naples, Italy.
Heliyon
|July 18, 2024
概括
从糖氨酸贝他因合成的新型抗泡剂通过减少超级可塑剂引起的泡来改善混凝土性能. 在含有12-14个碳原子的和脂肪醇中观察到最佳有效性.
科学领域:
- 材料科学 材料科学 材料科学
- 化学工程是化学工程的重要组成部分.
- 建筑化学 建筑化学
背景情况:
- 超级增塑剂增强了混凝土的性能,但增加了空气含量,导致泡.
- 泡对混凝土的机械性能和可加工性产生负面影响.
- 防泡剂对于控制水泥系统中的泡至关重要.
研究的目的:
- 合成由糖氨酸,贝他因和脂肪醇衍生的新型防泡剂.
- 评估这些合成抗泡在超塑性化剂溶液和水泥系统中的稳定性和有效性.
- 为了确定最佳的脂肪酒精链长度,以获得防泡效果.
主要方法:
- 从糖氨酸贝他因和各种脂肪醇合成以为基础的防泡剂.
- 使用1H NMR光谱分析合成产品的分析.
- 泡试验 (罗斯-迈尔斯方法) 评估超塑性溶液中的稳定性.
- 流表测试用于评估在水泥系统中的防泡效果.
- 图像分析 (图像J) 用于量化混凝土中的泡含量.
主要成果:
- 与商业产品相比,所有合成的防泡都表现出优越的性能.
- 来自和脂肪醇的防泡剂显示出特别高的疗效.
- 脂肪酒精碳链长度在12至14之间,可达到最佳性能.
- 链条长度过短或过长的酒精效果较差.
结论:
- 基于糖氨酸贝他因的新型抗泡剂在混凝土配方中提供了显著的改进.
- 脂肪酒精成分的链条长度对于防泡效率至关重要.
- 具有12-14个碳原子的和脂肪酒精代表了在混凝土中有效控制泡的最佳选择.
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