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Updated: Jun 20, 2025

Facile Preparation of 2Z,4E-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate
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符合性锁定诱导了对B-H和O-H键的酶选择性二甲基碳素插入,使用了阴离子Rh (I) /二烯催化剂

Weici Xu1, Takeshi Yamakawa1, Meiling Huang1

  • 1Shenzhen Grubbs Institute and Department of Chemistry, Southern University of Science and Technology, Shenzhen, 518055, China.

Angewandte Chemie (International ed. in English)
|July 18, 2024
PubMed
概括

研究人员开发了一种新的Rh(I) / 奇拉二烯催化剂,用于酶选择性碳转化. 该系统在B-H和O-H插入中实现了高选择性,克服了先前在二甲基碳化学中的局限性.

关键词:
B−H 键的插入方式O−H 键插入插入奇拉的日常生活这是一种二甲基碳烯 (diarylcarbene).是的元素之一.

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