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相关概念视频

Formation of Complex Ions03:45

Formation of Complex Ions

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A type of Lewis acid-base chemistry involves the formation of a complex ion (or a coordination complex) comprising a central atom, typically a transition metal cation, surrounded by ions or molecules called ligands. These ligands can be neutral molecules like H2O or NH3, or ions such as CN− or OH−. Often, the ligands act as Lewis bases, donating a pair of electrons to the central atom. These types of Lewis acid-base reactions are examples of a broad subdiscipline called coordination...
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Ion Exchange01:17

Ion Exchange

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Ion exchange chromatography separates charged molecules from a solution by reversibly exchanging them with mobile, or 'active', ions associated with the oppositely charged stationary phase. This method can be used to separate ions, soften and deionize water, and purify solutions. The polymers comprising the ion-exchange column are high-molecular-weight and chemically stable polymers, crosslinked to be porous and essentially insoluble. They are also functionalized with either acidic or...
572
Ionic Crystal Structures02:42

Ionic Crystal Structures

14.2K
Ionic crystals consist of two or more different kinds of ions that usually have different sizes. The packing of these ions into a crystal structure is more complex than the packing of metal atoms that are the same size.
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
14.2K
Molecular and Ionic Solids02:54

Molecular and Ionic Solids

17.1K
Crystalline solids are divided into four types: molecular, ionic, metallic, and covalent network based on the type of constituent units and their interparticle interactions.
Molecular Solids
Molecular crystalline solids, such as ice, sucrose (table sugar), and iodine, are solids that are composed of neutral molecules as their constituent units. These molecules are held together by weak intermolecular forces such as London dispersion forces, dipole-dipole interactions, or hydrogen bonds, which...
17.1K
Ionic Strength: Effects on Chemical Equilibria01:19

Ionic Strength: Effects on Chemical Equilibria

1.4K
The addition of an inert ionic compound increases the solubility of a sparingly soluble salt. For example, adding potassium nitrate to a saturated solution of calcium sulfate significantly enhances the solubility of calcium sulfate. Le Châtelier's principle cannot predict this shift in the equilibrium. Instead, this could be explained in terms of changes in the effective concentration of the ions in solution in the presence of added inert salt.
In this solution, the primary...
1.4K
Ionic Bonding and Electron Transfer02:48

Ionic Bonding and Electron Transfer

41.4K
Ions are atoms or molecules bearing an electrical charge. A cation (a positive ion) forms when a neutral atom loses one or more electrons from its valence shell, and an anion (a negative ion) forms when a neutral atom gains one or more electrons in its valence shell. Compounds composed of ions are called ionic compounds (or salts), and their constituent ions are held together by ionic bonds: electrostatic forces of attraction between oppositely charged cations and anions. 
41.4K

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In Situ Neutron Powder Diffraction Using Custom-made Lithium-ion Batteries
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双离子矩阵电解质及其对固体电解质的影响 Si极的介相抑制和演变

Saida Cora1, John T Vaughey2, Niya Sa1

  • 1Department of Chemistry, University of Massachusetts Boston, Boston, Massachusetts 02125, United States.

ACS applied materials & interfaces
|July 18, 2024
PubMed
概括

在离子电解质中引入离子显著降低了阳极上的固体电解质介相 (SEI) 增长. 这种稳定通过控制SEI演变和减轻副作用反应来提高电池性能和寿命.

关键词:
在 EQCM-D 中.离子电池是一种离子电池.在SEI中抑制SEI的抑制.双离子电解质二元电离子电解质阳极是一种阳极.固体电解质相间阶段

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科学领域:

  • 材料科学 材料科学 材料科学
  • 电化学 电化学 电化学
  • 电池技术 电池技术

背景情况:

  • 不稳定的固体电解质间相 (SEI) 形成阻碍了 (Si) 阳极在高能量密度电池中的商业化.
  • 控制SEI的增长对于改善Si电池的循环寿命和安全至关重要.

研究的目的:

  • 调查二进制阴子矩阵 (Mg2++Li+) 在SEI发展和Si阳极上的演变中的作用.
  • 了解Mg2+如何影响SEI形成机制和电化学稳定性.

主要方法:

  • 在Mg2++Li+二进制电解质中对Si阳极进行电化学研究.
  • 在电化学循环过程中分析SEI的组成,生长和演变.
  • 离子溶解环境和相间性质的表征.

主要成果:

  • 补充Mg2+可通过抑制溶剂减少 (例如,乙烯碳酸盐) 来显著减少70%的初始SEI生长.
  • 化后的SEI生长减少了大约80%,包括Mg2+.
  • 2+稳定了深化Si相,导致SEI受控生长,更加刚性和均的SEI,并消除了复杂的Li-Si形成.

结论:

  • Mg2++Li二进制阴子矩阵有效地控制了Si阳极上的SEI形成和演变.
  • 2+离子的变化溶解,导致一个不同的,更稳定的SEI.
  • 这一战略为提高下一代基于Si的电池系统的性能和寿命提供了一条途径.