Yb/Si挫败了易斯对与一个不稳定的纳甲桥
Cheng Xu1, Sixuan Zhao2, Heng Zhang2
1Spin-X Institute, School of Chemistry and Chemical Engineering, State Key Laboratory of Luminescent Materials and Devices Guangdong-Hong Kong-Macao Joint Laboratory of Optoelectronic and Magnetic Functional Materials South China University of Technology, Guangzhou 510641, P. R. China. yaofchen@scut.edu.cn.
概括
研究人员合成了第一个稀土金属/挫败的易斯对 (RE/Si FLPs),特别是Yb/Si FLPs. 这些新型化合物反应形成新的西林基转移产物.
科学领域:
- 有机金属化学 有机金属化学
- 材料科学 材料科学 材料科学
- 稀土化学 稀土化学
背景情况:
- 丧的易斯对 (FLP) 是反应性物种,在催化和小分子激活中具有应用.
- 稀土元素为化学结合提供独特的电子特性.
研究的目的:
- 为了合成和表征第一个稀土金属/挫败了易斯对 (RE/Si FLPs).
- 研究这些新型RE/Si FLPs与小分子的反应性.
主要方法:
- / (Yb/Si) 的合成挫败了易斯对.
- 使用确定Yb-Si键距离 (3.553.72 Å) 的技术进行表征.
- 与三硫化和阿里尔异酸盐的反应研究.
主要成果:
- 成功合成Yb/Si FLPs,代表了RE/Si FLPs的第一个例子.
- 观察与三硫化和阿里尔异酸盐的反应.
- 通过纳夫他林解离形成新型西利林组转移产物.
结论:
- Yb/Si FLPs是稳定的,可以合成使用.
- 这些FLP表现出独特的反应性,使得西林基转移成为可能.
- 在主要组化学中为稀土元素应用开辟了新的途径.
相关概念视频
Exceptions to the Octet Rule
28.1K
Many covalent molecules have central atoms that do not have eight electrons in their Lewis structures. These molecules fall into three categories:
28.1K
Lewis Structures of Molecular Compounds and Polyatomic Ions
34.7K
To draw Lewis structures for complicated molecules and molecular ions, it is helpful to follow a step-by-step procedure as outlined:
34.7K
Lewis Symbols and the Octet Rule
63.6K
Chemical bonds are complex interactions between two or more atoms or ions, which reduce the potential energy of the molecule. Gilbert N. Lewis developed a model called the Lewis model that simplified the depiction of chemical bond formation and provided straightforward explanations for the chemical bonds seen in most common compounds.
63.6K
Valence Bond Theory
32.2K
Overview of Valence Bond Theory
32.2K
VSEPR Theory and the Effect of Lone Pairs
42.1K
Effect of Lone Pairs of Electrons on Molecule Geometry
42.1K
Hybridization of Atomic Orbitals I
46.9K
The mathematical expression known as the wave function, ψ, contains information about each orbital and the wavelike properties of electrons in an isolated atom. When atoms are bound together in a molecule, the wave functions combine to produce new mathematical descriptions that have different shapes. This process of combining the wave functions for atomic orbitals is called hybridization and is mathematically accomplished by the linear combination of atomic orbitals. The new orbitals that...
46.9K


